Structural and electrochemical characterization of Li1.2Ni x Co x Mn0.8-aEuroparts per thousand2x O2 (x=0.128, 0.16, and 0.2) as cathode materials for lithium-ion batteries

被引:6
作者
Xiang, Yanhong [1 ]
Yin, Zhoulan [1 ]
Li, Xinhai [2 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
[2] Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China
关键词
Carbonate precipitation; Ordered addition method; Li-rich material; HIGH-CAPACITY; ELECTRODES M; LI-ION; COPRECIPITATION; PERFORMANCE; MN; NI; IRRADIATION;
D O I
10.1007/s11581-013-0971-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Li1.2Ni (x) Co (x) Mn0.8 -aEuro parts per thousand 2x O-2 (x = 0.128, 0.16, and 0.2) cathode materials have been synthesized by a simple carbonate precipitation method followed by high-temperature calcination. The effects of the transition metal content on the structure, physical property, and electrochemical performance of the samples have been investigated. As the manganese content increases, we observed not only a well-ordered layered structure and uniform morphology but also remarkable improvements in capacity and better cycling properties.
引用
收藏
页码:157 / 162
页数:6
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