Structural and electrochemical characterization of Li1.2Ni x Co x Mn0.8-aEuroparts per thousand2x O2 (x=0.128, 0.16, and 0.2) as cathode materials for lithium-ion batteries

被引:6
作者
Xiang, Yanhong [1 ]
Yin, Zhoulan [1 ]
Li, Xinhai [2 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
[2] Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China
关键词
Carbonate precipitation; Ordered addition method; Li-rich material; HIGH-CAPACITY; ELECTRODES M; LI-ION; COPRECIPITATION; PERFORMANCE; MN; NI; IRRADIATION;
D O I
10.1007/s11581-013-0971-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Li1.2Ni (x) Co (x) Mn0.8 -aEuro parts per thousand 2x O-2 (x = 0.128, 0.16, and 0.2) cathode materials have been synthesized by a simple carbonate precipitation method followed by high-temperature calcination. The effects of the transition metal content on the structure, physical property, and electrochemical performance of the samples have been investigated. As the manganese content increases, we observed not only a well-ordered layered structure and uniform morphology but also remarkable improvements in capacity and better cycling properties.
引用
收藏
页码:157 / 162
页数:6
相关论文
共 50 条
  • [1] Structural and electrochemical characterization of Li1.2NixCoxMn0.8 − 2xO2 (x = 0.128, 0.16, and 0.2) as cathode materials for lithium-ion batteries
    Yanhong Xiang
    Zhoulan Yin
    Xinhai Li
    Ionics, 2014, 20 : 157 - 162
  • [2] Fe doped Li1.2Mn0.6-x/2Ni0.2-x/2FexO2 (x≤0.1) as cathode materials for lithium-ion batteries
    Liu, Xiaoyu
    Huang, Tao
    Yu, Aishui
    ELECTROCHIMICA ACTA, 2014, 133 : 555 - 563
  • [3] Influences of transition metal on structural and electrochemical properties of Li[NixCoyMnz]O2 (0.6≤x≤0.8) cathode materials for lithium-ion batteries
    Pan, Cheng-chi
    Zhu, Yi-rong
    Yang, Ying-chang
    Hou, Hong-shuai
    Jing, Ming-jun
    Song, Wei-xin
    Yang, Xu-ming
    Ji, Xiao-bo
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2016, 26 (05) : 1396 - 1402
  • [4] Synthesis, characterization and electrochemical performance of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode materials for lithium-ion batteries
    Jin, Xue
    Xu, Qunjie
    Yuan, Xiaolei
    Zhou, Luozeng
    Xia, Yongyao
    ELECTROCHIMICA ACTA, 2013, 114 : 605 - 610
  • [5] Influence of Co increment on the electrochemical properties of Li1.2[Mn0.52-0.5xNi0.2-0.5xCo0.08+x]O2 cathode materials for lithium-ion batteries
    Wang, Chunlei
    Zhou, Fei
    Ren, Chong
    Kong, Jizhou
    Tang, Zhou
    Li, Junxiu
    Yu, Chao
    Tang, Wei-Ping
    JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 643 : 223 - 230
  • [6] Electrochemical and structural characterization of carbon coated Li1.2Mn0.56Ni0.16Co0.08O2 and Li1.2Mn0.6Ni0.2O2 as cathode materials for Li-ion batteries
    Nayak, Prasant Kumar
    Grinblat, Judith
    Levi, Mikhael
    Aurbach, Doron
    ELECTROCHIMICA ACTA, 2014, 137 : 546 - 556
  • [7] Effect of lithium content on electrochemical property of Li1+x(Mn0.6Ni0.2Co0.2)1-xO2 (0≤x≤0.3) composite cathode materials for rechargeable lithium-ion batteries
    Pan, Cheng-chi
    Yang, Ying-chang
    Hou, Hong-shuai
    Jing, Ming-jun
    Zhu, Yi-rong
    Song, Wei-xin
    Ji, Xiao-bo
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2018, 28 (01) : 145 - 150
  • [8] Synthesis and electrochemical characteristics of Li1.2(Ni0.2Mn0.6)x(Co0.4Mn0.4)y(Ni0.4Mn0.4)1-x-yO2 (0 ≤ x plus y ≤ 1) cathode materials for lithium ion batteries
    Zhang, Chao
    Hou, Peiyu
    Shi, Xixi
    Song, Dawei
    Song, Jishun
    Zhang, Lianqi
    RSC ADVANCES, 2015, 5 (45): : 36015 - 36021
  • [9] Understanding effects of lithium content on structural and electrochemical characteristics of Li1+xMn0.7Ni0.2Co0.1O2.25+x/2 cathode materials for lithium-ion batteries
    Ma, Quanxin
    Yin, Shibo
    Ding, Fei
    Meng, Junxia
    Zhong, Shengwen
    Dai, Changsong
    MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2019, 246 : 143 - 152
  • [10] Enhanced electrochemical performances of Li1.2Ni0.2Mn0.6O2 cathode materials by coating LiAlO2 for lithium-ion batteries
    Zhang, L. L.
    Chen, J. J.
    Cheng, S.
    Xiang, H. F.
    CERAMICS INTERNATIONAL, 2016, 42 (01) : 1870 - 1878