Nonconventional catalysts for isotactic propene polymerization in solution developed by using high-throughput-screening technologies

被引：227
作者：
Boussie, Thomas R.
Diamond, Gary M.
Goh, Christopher
Hall, Keith A.
LaPointe, Anne M.
Leclerc, Margarete K.
Murphy, Vince
Shoemaker, James A. W.
Turner, Howard
Rosen, Robert K.
Stevens, James C.
Alfano, Francesca
Busico, Vincenzo
Cipullo, Roberta
Talarico, Giovanni
机构：
[1] Symx Technol Inc, Santa Clara, CA 95091 USA
[2] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy
[3] Dow Chem Co USA, Freeport, TX 77541 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 20期
关键词：
hafnium; high-throughput screening; nitrogen heterocycles; polymerization; tacticity;
D O I：
10.1002/anie.200600240
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) A textbook example of catalyst discovery, optimization, and commercial implementation is provided with the discovery of a class of Hf-based non-metallocene olefin polymerization catalysts (see picture; Hf orange sphere, N blue, C(Me) green, C orange), their advanced high-throughput screening, and their industrial application in a high-temperature solution process for the production of highly isotactic polypropylene based materials. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：3278 / 3283
页数：6
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