Cleavage of C-C and C-Si σ-Bonds and Their Intramolecular Exchange

被引：120
作者：
Ishida, Naoki [1 ]
Ikemoto, Wataru [1 ]
Murakami, Masahiro [1 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 16期
关键词：
CARBON-CARBON BOND; NICKEL-CATALYZED CARBOCYANATION; COUPLING REACTIONS; PALLADIUM; SILACYCLOBUTANES; ACTIVATION; METHYLENECYCLOPROPANES; CHEMISTRY; BIPHENYLENE; PLATINUM;
D O I：
10.1021/ja502601g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C-C and C-Si sigma-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.
引用
收藏
页码：5912 / 5915
页数：4
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