Cleavage of C-C and C-Si σ-Bonds and Their Intramolecular Exchange

被引：120

作者：

Ishida, Naoki ^{[1
]}

Ikemoto, Wataru ^{[1
]}

Murakami, Masahiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 16期

关键词：

CARBON-CARBON BOND; NICKEL-CATALYZED CARBOCYANATION; COUPLING REACTIONS; PALLADIUM; SILACYCLOBUTANES; ACTIVATION; METHYLENECYCLOPROPANES; CHEMISTRY; BIPHENYLENE; PLATINUM;

D O I：

10.1021/ja502601g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C-C and C-Si sigma-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.

引用

页码：5912 / 5915

页数：4

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