Cyclopalladated ferrocenylimines: highly active catalysts for Heck reactions

被引：76

作者：

Wu, YJ ^{[1
]}

Hou, JJ ^{[1
]}

Yun, HY ^{[1
]}

Cui, XL ^{[1
]}

Yuan, RJ ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 637卷

基金：

中国国家自然科学基金;

关键词：

cyclometallation; ferrocenylimine; Heck reaction;

D O I：

10.1016/S0022-328X(01)00967-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel kind of ferrocene moiety containing palladacycle catalysts 1 and 2 was synthesized and applied to Heck arylation. High yields, turnover numbers and regioselectivity were achieved in moderate conditions. When 2.73 x 10(-8) mot catalyst 2 was used to catalyze arylation of 0.1 mol iodobenzene with butyl acrylate, optimal results were obtained with 3.6 x 10(6) turnover number and 99% yield. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：793 / 795

页数：3

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