Multifarious roles of carbon quantum dots in heterogeneous photocatalysis

被引:128
作者
Lu, Kang-Qiang [1 ,2 ]
Quan, Quan [1 ,2 ]
Zhang, Nan [1 ,2 ]
Xu, Yi-Jun [1 ,2 ]
机构
[1] Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
[2] Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350108, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon quantum dots; Multifarious roles; Photocatalysis applications; Solar energy conversion; VISIBLE-LIGHT IRRADIATION; NEAR-INFRARED IRRADIATION; SOLAR-ENERGY CONVERSION; UP-CONVERSION; ULTRASONIC PREPARATION; EMERGENT NANOLIGHTS; HYBRID NANOSHEETS; NICKEL-CATALYST; GRAPHENE; COMPOSITES;
D O I
10.1016/j.jechem.2016.09.015
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
As a new member of carbon material family, carbon quantum dots (CQDs) have attracted tremendous attentions for their potentials in the heterogeneous photocatalysis applications. Due to the unique microstructure and optical properties, the roles of CQDs played in the CQDs-based photocatalytic systems have been found to be diverse with the continuous researches in this regard. Herein, we provide a concise minireview to elaborate the multifarious roles of CQDs in photocatalysis, including photoelectron mediator and acceptor, photosensitizer, photocatalyst, reducing agent for metal salt, enhancing adsorption capacity and spectral converter. In addition, the perspectives on future research trends and challenges are proposed, which are anticipated to stimulate further research into this promising field on designing a variety of efficient CQDs-based photocatalysts for solar energy conversion. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B. V. and Science Press. All rights reserved.
引用
收藏
页码:927 / 935
页数:9
相关论文
共 94 条
[81]   Carbon quantum dots/TiO2 composites for efficient photocatalytic hydrogen evolution [J].
Yu, Huijun ;
Zhao, Yufei ;
Zhou, Chao ;
Shang, Lu ;
Peng, Yong ;
Cao, Yinhu ;
Wu, Li-Zhu ;
Tung, Chen-Ho ;
Zhang, Tierui .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (10) :3344-3351
[82]   Photocatalytic water splitting for solar hydrogen generation: fundamentals and recent advancements [J].
Yuan, Lan ;
Han, Chuang ;
Yang, Min-Quan ;
Xu, Yi-Jun .
INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 2016, 35 (01) :1-36
[83]   Photocatalytic conversion of CO2 into value-added and renewable fuels [J].
Yuan, Lan ;
Xu, Yi-Jun .
APPLIED SURFACE SCIENCE, 2015, 342 :154-167
[84]   Carbon quantum dots/Ag3PO4 complex photocatalysts with enhanced photocatalytic activity and stability under visible light [J].
Zhang, Hengchao ;
Huang, Hui ;
Ming, Hai ;
Li, Haitao ;
Zhang, Lili ;
Liu, Yang ;
Kang, Zhenhui .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (21) :10501-10506
[85]   Fe2O3/carbon quantum dots complex photocatalysts and their enhanced photocatalytic activity under visible light [J].
Zhang, Hengchao ;
Ming, Hai ;
Lian, Suoyuan ;
Huang, Hui ;
Li, Haitao ;
Zhang, Lili ;
Liu, Yang ;
Kang, Zhenhui ;
Lee, Shuit-Tong .
DALTON TRANSACTIONS, 2011, 40 (41) :10822-10825
[86]   Graphene-metal-oxide composites for the degradation of dyes under visible light irradiation [J].
Zhang, Jintao ;
Xiong, Zhigang ;
Zhao, X. S. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (11) :3634-3640
[87]   Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalysts [J].
Zhang, Nan ;
Yang, Min-Quan ;
Liu, Siqi ;
Sun, Yugang ;
Xu, Yi-Jun .
CHEMICAL REVIEWS, 2015, 115 (18) :10307-10377
[88]   CdS-graphene nanocomposites as visible light photocatalyst for redox reactions in water: A green route for selective transformation and environmental remediation [J].
Zhang, Nan ;
Yang, Min-Quan ;
Tang, Zi-Rong ;
Xu, Yi-Jun .
JOURNAL OF CATALYSIS, 2013, 303 :60-69
[89]   Effective Charge Carrier Utilization in Photocatalytic Conversions [J].
Zhang, Peng ;
Wang, Tuo ;
Chang, Xiaoxia ;
Gong, Jinlong .
ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (05) :911-921
[90]   Graphene Transforms Wide Band Gap ZnS to a Visible Light Photocatalyst. The New Role of Graphene as a Macromolecular Photosensitizer [J].
Zhang, Yanhui ;
Zhang, Nan ;
Tang, Zi-Rong ;
Xu, Yi-Jun .
ACS NANO, 2012, 6 (11) :9777-9789