Thermodynamic description of the system Ag-Sn-Zn

被引:8
作者
Vassilev, G. [1 ]
Gandova, V. [2 ]
Milcheva, N. [1 ]
Wnuk, G. [3 ]
机构
[1] Paisij Hilendarski Univ Plovdiv, Fac Chem, BG-4000 Plovdiv, Bulgaria
[2] Univ Food Technol, Inorgan & Phys Chem Dept, Plovdiv 4000, Bulgaria
[3] Rzeszow Univ Technol, Rzeszow, Poland
来源
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2013年 / 43卷
关键词
Thermodynamics; Phase equilibrium; Computational modeling; Silver alloys; Solders; PHASE-EQUILIBRIA; ZINC;
D O I
10.1016/j.calphad.2013.03.003
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental data about phase equillibria (e.g. phase boundaries location, invariant equilibria temperatures, etc.) and thermochemical quantities (i.e. thermodynamic activities, liquid phase enthalpies of formation) of the system Ag-Sn-Zn have been considered simultaneously by using CALPHAD approach. Recently reassessed thermodynamic stability of the (fcc-Sn)-phase has been used. Optimized thermodynamic parameters allowing the calculation of the respective ternary phase diagram have been derived. Unlike a previous optimization the solubilities of the third constituents in the respective binary phases have been taken into account (i.e. Zn-solubility in Ag-Sn based intermetallic compounds and Sn-solubility in Ag-Zn phases). Calculated isothermal sections and thermochemical values have been compared to corresponding experimental data in order to check up the agreement. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:133 / 138
页数:6
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