Novel planar and sandwich-type complexes of substituted tetrathieno[2,3-b] porphyrazine: Synthesis and investigation of properties

被引：23

作者：

Dubinina, Tatiana V. ^{[1
,2
]}

Dyumaeva, Dania V. ^{[1
]}

Trashin, Stanislav A. ^{[2
]}

Sedova, Marina V. ^{[3
]}

Dudnik, Alexander S. ^{[4
]}

Borisova, Natalia E. ^{[1
]}

Tomilova, Larisa G. ^{[1
,2
]}

Zefirov, Nikolay S. ^{[1
,2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[2] Russian Acad Sci, Inst Physiol Act Cpds, Chernogolovka 142432, Moscow Region, Russia

[3] Russian Acad Sci, Inst Theoret & Appl Electromagnet, Moscow, Russia

[4] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

DYES AND PIGMENTS | 2013年 / 96卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

Porphyrazine; Thiophene; Triple-decker complex; Lanthanide; AFM; NMR; ELECTROCHEMICAL PROPERTIES; PHTHALOCYANINES; NAPHTHALOCYANINES; SEMICONDUCTOR; THIOPHENE; ANALOGS;

D O I：

10.1016/j.dyepig.2012.11.008

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient synthetic approach to a novel substituted tetrathieno[2,3-b]porphyrazine, its Mg, Zn, Lu complexes and a Lu triple-decker complex was developed. Spectral properties and aggregation phenomena of the target compounds were investigated by UV/Vis spectroscopy and atomic force microscopy (AFM). Electrochromic behaviour of the Zn complex was studied by electrochemistry and spectroelectrochemistry. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：699 / 704

页数：6

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