Dynamic covalent templated-synthesis of [c2] daisy chains

被引:13
|
作者
Bozdemir, O. Altan [1 ]
Barin, Gokhan [1 ]
Belowich, Matthew E. [1 ]
Basuray, Ashish N. [1 ]
Beuerle, Florian [1 ]
Stoddart, J. Fraser [1 ,2 ,3 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Korea Adv Inst Sci & Technol, NanoCentury KAIST Inst, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, Grad Sch EEWS WCU, Taejon 305701, South Korea
关键词
DIRECTED SYNTHESIS; DONOR-ACCEPTOR; INTERLOCKED MOLECULES; CHEMISTRY; MACROCYCLE; HERMAPHRODITE; DRIVEN; JANUS; 1ST;
D O I
10.1039/c2cc35522a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A couple of [c2] daisy chains have been assembled in each case from four components in quantitative yields at room temperature in acetonitrile as a result of the self-templated clippings of their [24]crown-8 rings by reversible imine bond formation around secondary dialkylammonium recognition sites in their stalks.
引用
收藏
页码:10401 / 10403
页数:3
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