Asymmetric allylic alkylation catalyzed by palladium complexes with a new chiral bisphosphine ligand

被引：26
|
作者：
Longmire, JM [1 ]
Zhu, GX [1 ]
Zhang, XM [1 ]
机构：
[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 03期
关键词：
D O I：
10.1016/S0040-4039(96)02329-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel, chiral bisphosphine ligand has been synthesized and its palladium complexes have been used in asymmetric allylic alkylation. High reactivity and moderate selectivity have been realized in the reaction between 1,3-diphenyl-2-propenyl acetate and dimethyl malonate. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：375 / 378
页数：4
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