Laser excited metastable states of acetylene in the 5.5-5.7 eV region

被引：22

作者：

Humphrey, SJ ^{[1
]}

Morgan, CG ^{[1
]}

Wodtke, AM ^{[1
]}

Cunningham, KL ^{[1
]}

Drucker, S ^{[1
]}

Field, RW ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 01期

关键词：

D O I：

10.1063/1.474351

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experimental results are presented which show UV excitation to metastable states of C2H2 above and below the dissociation limit. A strong S-1-T-3 interaction, located close in energy to the S(1)3 nu(3) (trans-bend) vibrational level is detected. A ''gateway mediated intersystem crossing'' singlet-tripler coupling mechanism explains the results. (C) 1997 American Institute of Physics.

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页码：49 / 53

页数：5

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