Intense violet-blue emitting (CaCl2/SiO2) :: Eu2+ phosphor powders for applications in UV-LED based phototherapy illuminators

被引:21
作者
Hao, Zhendong [1 ,2 ]
Zhang, Jiahua [1 ]
Zhang, Xia [1 ]
Ren, Xinguang [1 ]
Luo, Yongshi [1 ]
Lu, Shaozhe [1 ]
Wang, Xiaojun [1 ,3 ]
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys CIOMP, Key Lab Excited State Proc, Changchun 130033, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] Georgia So Univ, Dept Phys, Statesboro, GA 30460 USA
基金
中国国家自然科学基金;
关键词
Chlorine compounds - Silica - Light emission - Solid state reactions - Light emitting diodes;
D O I
10.1088/0022-3727/41/18/182001
中图分类号
O59 [应用物理学];
学科分类号
摘要
An intense violet-blue emitting (CaCl2/SiO2) : Eu2+ phosphor with a composition of 25% CaCl2 and 75% SiO2 is prepared by a solid state reaction. The phosphor emits at 427 nm with a narrow bandwidth of 21 nm. The photoluminescence (PL) intensities and fluorescence lifetimes are studied as a function of Eu2+ concentrations. It is observed that the PL intensity of (CaCl2/SiO2) : Eu2+ can be 30% higher than that of commercial Sr2P2O7 : Eu2+ phosphor under 395 nm excitation. (CaCl2/SiO2) : Eu2+ would be a promising new phosphor for converting near-ultraviolet radiation to violet-blue emission for a novel phototherapy illuminator using a near-ultraviolet (similar to 395 nm) light emitting diode as the excitation source.
引用
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页数:4
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