An Efficient Guanylation of Aromatic Amines Catalyzed by Samarium Diiodide

被引：26

作者：

Zhu Xuehua ^{[1
]}

Xu Fan ^{[1
]}

Shen Qi ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2009年 / 27卷 / 01期

基金：

中国国家自然科学基金;

关键词：

guanidine; synthesis; samarium diiodide; catalysis; NATURAL GUANIDINE DERIVATIVES; SOLID-PHASE SYNTHESIS; ONE-POT SYNTHESIS; SUBSTITUTED GUANIDINES; ASYMMETRIC CATALYSIS; LANTHANIDE COMPLEXES; ORGANIC-SYNTHESIS; SECONDARY-AMINES; METAL-COMPLEXES; N-H;

D O I：

10.1002/cjoc.200990017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient guanylation of aromatic amine with carbodiimide in the presence of a catalytic amount of samarium diiodide, a Lewis-acid type precatalyst readily accessible, was developed. The reaction was carried out under mild conditions giving a variety of guanidines in good to excellent yields.

引用

页码：19 / 22

页数：4

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