Extraction Properties of Nickel (II) with Polymeric Particles with Interconnected Spherical Pores Impregnating with LIX84-I

被引：9

作者：

Kitabayashi, Takuro ^{[1
]}

Sana, Takashi ^{[1
]}

Kiyoyama, Shiro ^{[2
]}

Takei, Takayuki ^{[3
]}

Yoshida, Masahiro ^{[3
]}

Shiomori, Koichiro ^{[1
]}

机构：

[1] Miyazaki Univ, Dept Appl Chem, Miyazaki 8892192, Japan

[2] Miyakonojyo Natl Coll Technol, Dept Chem Sci & Engn, Miyakonojo 8858567, Japan

[3] Kagoshima Univ, Grad Sch Engn, Dept Chem Engn, Kagoshima 8900065, Japan

来源：

SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN | 2013年 / 20卷

关键词：

IN-SITU POLYMERIZATION; POLYSULFONE MICROCAPSULES; PRECIOUS METALS; RESINS SIRS; SEPARATION; RECOVERY; CHLORIDE; REMOVAL; COLUMN; MEDIA;

D O I：

10.15261/serdj.20.137

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-(2-hydroxyl-5-nonyphenypethanone oxime (LIX84-I) was impregnated into polymeric particles with interconnected spherical pores by the solvent evaporation method. Divinylbenzene was used as a wall material and polymerized in the organic phase of a (W/O/W) emulsion by free radical polymerization. The diameter of the polymeric particles was almost constant at around 208 +/- 26 mu m. The impregnated yield of LIX84-I in the polymeric particles was higher than 80% in all preparation conditions. The extraction of Ni(II) with the polymeric particles impregnated with LIX84-I sharply increased at pH values higher than 6. It is confirmed that three molecules of LIX84-I reacted with one Ni(II) ion by quantitative analysis of the relationship between the maximum amounts of Ni(II) extracted and the amount of LIX84-I impregnated in the polymeric particles. The extraction rate of Ni(II) was effectively accelerated by the presence of the interconnected-spherical pores in the inside of the polymeric particles.

引用

页码：137 / 147

页数：11

共 27 条

[1] Separation of organic acids by newly developed polysulfone microcapsules containing triotylamine [J].

Gong, XC ;

Luo, GS ;

Yang, WW ;

Wu, FY .

SEPARATION AND PURIFICATION TECHNOLOGY, 2006, 48 (03) :235-243

[2]

Gong XC, 2009, J MICROENCAPSUL, V26, P104, DOI [10.1080/02652040802176357, 10.1080/02652040802176357 ]

[3] SELECTIVE RECOVERY OF COPPER, COBALT, AND NICKEL FROM AQUEOUS CHLORIDE MEDIA USING SOLVENT IMPREGNATED RESINS [J].

Guo, Fuqiang ;

Nishihama, Syouhei ;

Yoshizuka, Kazuharu .

SOLVENT EXTRACTION AND ION EXCHANGE, 2012, 30 (06) :579-592

[4] Adsorption of Europium(III) by Solvent Impregnated Kapok Fibers Containing 2-Ethylhexyl Phosphonic Acid Mono-2-Ethylhexyl Ester [J].

Higa, Natsuki ;

Nishihama, Syouhei ;

Yoshizuka, Kazuharu .

SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2011, 18 :187-192

[5] Separation of Ni and Co Using Microcapsules Containing an Extractant [J].

Hirao, Shinichi ;

Matsumoto, Michiaki ;

Kondo, Kazuo .

KAGAKU KOGAKU RONBUNSHU, 2010, 36 (05) :457-465

[6] Removal of Bi, Cd, Co, Cu, Fe, Ni, Pb, and Zn from an aqueous nitrate medium with bis(2-ethylhexyl)phosphoric acid impregnated kapok fiber [J].

Huynh, HT ;

Tanaka, M .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (17) :4050-4054

[7] Preparation of cross-linked microcapsules with spherical pores by in-situ polymerization in (W/O/W) emulsion system [J].

Ijichi, K ;

Hatate, Y ;

Kiyoyama, S ;

Shiomori, K ;

Baba, Y ;

Kawano, Y .

KAGAKU KOGAKU RONBUNSHU, 1997, 23 (02) :303-306

[8]

Inoue A., 1988, SHIGEN TO SOZAI, V114, P819

[9] Packed column study of the sorption of hexavalent chromium by novel solvent impregnated resins containing aliquat 336:: Effect of chloride and sulfate ions [J].

Kabay, N ;

Solak, Ö ;

Arda, M ;

Topal, Ü ;

Yüksel, M ;

Trochimczuk, A ;

Streat, M .

REACTIVE & FUNCTIONAL POLYMERS, 2005, 64 (02) :75-82

[10] Removal of chromate by solvent impregnated resins (SIRs) stabilized by coating and chemical crosslinking. I. Batch-mode sorption studies [J].

Kabay, N ;

Arda, M ;

Trochimczuk, A ;

Streat, M .

REACTIVE & FUNCTIONAL POLYMERS, 2004, 59 (01) :9-14

← 1 2 3 →