The multiple role of inorganic and organic additives in the degradation of reactive green 12 by UV/chlorine advanced oxidation process

The impact of various mineral anions, diverse organic substrates and different environmental matrices on the removal of C.I. reactive green 12 (RG12), a refractory textile dye, by UV/chlorine emerging advanced oxidation process (AOP) was performed. The co-exposure of RG12 (20 mg L-1) to UV and chlorine (0.5 mM) at pH 5 produced a strong synergism on the degradation rate. Radical probe technique showed that(BLACK CIRCLE)OH and Cl(2)(BLACK CIRCLE-)were the main source of the synergistic effect. Bromide, bicarbonate and chloride at small dosage, i.e. 1 mM, enhanced the rate of RG12 degradation, but higher concentrations of these anions quenched the degradation process. Sulphate anions did not alter the degradation rate of the dye, but nitrite quenched it at similar to 90%. The inhibiting effect of nitrate appeared only at advanced reaction time (>1 min).On the other hand, natural organic matter (NOM) reduced effectively the degradation rate. Besides, SDS surfactant at only 1 mu M accelerated the degradation efficiency by similar to 12%. However, Tween 80 has shown an insignificant effect, whereas reductions of 10% and 30% were recorded by Triton X100 and Tween 20, respectively. The RG12-degradation rate was not affected in the mineral water, but it was drastically improved in seawater. Conversely, a huge drop in the RG12-degradation efficiency was obtained in the wastewater effluent. UV/chlorine process is highly viable for degrading pollutant in matrices free of NOM. However, the process losses its potential application in matrices riche of NOM.