Two-Step Annealing Study of Cuprous Oxide for Photovoltaic Applications

被引:5
作者
Lloyd, Michael A. [1 ]
Siah, Sin-Cheng [1 ]
Brandt, Riley E. [1 ]
Serdy, James [1 ]
Johnston, Steve W. [2 ]
Hofstetter, Jasmin [1 ]
Lee, Yun Seog [1 ]
McCandless, Brian [3 ]
Buonassisi, Tonio [1 ]
机构
[1] MIT, Cambridge, MA 02139 USA
[2] Natl Renewable Energy Lab, Golden, CO 80401 USA
[3] Inst Energy Convers, Newark, DE 19711 USA
来源
IEEE JOURNAL OF PHOTOVOLTAICS | 2015年 / 5卷 / 05期
基金
美国国家科学基金会; 新加坡国家研究基金会;
关键词
Annealing; charge carrier density; charge carrier mobility; copper compounds; photoconductivity; photovoltaic cells; X-ray diffraction; BUFFER LAYER; CU2O;
D O I
10.1109/JPHOTOV.2015.2455332
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The properties of large grain cuprous oxide (Cu2O) foils are explored after the implementation of a controlled post-growth annealing process. P-type foils with a wide range of carrier density are demonstrated, enabling a promising processing window for wide bandgap solar cell devices. Hall measurements at room temperature show increased majority carrier concentration after nitrogen annealing and a reduction in mobility. The progressive change in resistivity with annealing temperature is shown, with values approaching 100 Omega.cm. Carrier recombination, measured by microwave photoconductance decay, shows a discrete change upon annealing.
引用
收藏
页码:1476 / 1481
页数:6
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