Nitrogen-Rich Triptycene-Based Porous Polymer for Gas Storage and Iodine Enrichment

被引：157

作者：

Ma, Hui ^{[1
]}

Chen, Jing-Jing ^{[1
]}

Tan, Liangxiao ^{[2
]}

Bu, Jian-Hua ^{[3
]}

Zhu, Yanhong ^{[1
]}

Tan, Bien ^{[2
]}

Zhang, Chun ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Natl Engn Res Ctr Nanomed, Coll Life Sci & Technol, Key Lab Mol Biophys,Minist Educ, Wuhan 430074, Hubei, Peoples R China

[2] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China

[3] Xian Modern Chem Res Inst, Xian 710065, Peoples R China

来源：

ACS MACRO LETTERS | 2016年 / 5卷 / 09期

基金：

中国国家自然科学基金;

关键词：

HEXAPHENYLBENZENE BASED TRIPTYCENE; MICROPOROUS POLYMERS; ORGANIC FRAMEWORKS; SURFACE-AREA; MONOMER SYNTHESIS; I-2; SORPTION; CO2; CAPTURE; WASTE FORMS; ADSORPTION; NETWORKS;

D O I：

10.1021/acsmacrolett.6b00567

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new kind of nitrogen-rich triptycene-based porous polymer (NTP) with high surface area of up to 1067 m(2) g(-1) was synthesized by a modified Yamamoto-type Ullmann cross-coupling reaction. Having structure features of expanded conjugated area and nitrogen atoms doping in polymer networks, the NTP displays extraordinary gas storage ability and excellent iodine adsorption capability.

引用

页码：1039 / 1043

页数：5

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