Nitrogen-Rich Triptycene-Based Porous Polymer for Gas Storage and Iodine Enrichment

被引：151
|
作者：
Ma, Hui [1 ]
Chen, Jing-Jing [1 ]
Tan, Liangxiao [2 ]
Bu, Jian-Hua [3 ]
Zhu, Yanhong [1 ]
Tan, Bien [2 ]
Zhang, Chun [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Natl Engn Res Ctr Nanomed, Coll Life Sci & Technol, Key Lab Mol Biophys,Minist Educ, Wuhan 430074, Hubei, Peoples R China
[2] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China
[3] Xian Modern Chem Res Inst, Xian 710065, Peoples R China
来源：
ACS MACRO LETTERS | 2016年 / 5卷 / 09期
基金：
中国国家自然科学基金;
关键词：
HEXAPHENYLBENZENE BASED TRIPTYCENE; MICROPOROUS POLYMERS; ORGANIC FRAMEWORKS; SURFACE-AREA; MONOMER SYNTHESIS; I-2; SORPTION; CO2; CAPTURE; WASTE FORMS; ADSORPTION; NETWORKS;
D O I：
10.1021/acsmacrolett.6b00567
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new kind of nitrogen-rich triptycene-based porous polymer (NTP) with high surface area of up to 1067 m(2) g(-1) was synthesized by a modified Yamamoto-type Ullmann cross-coupling reaction. Having structure features of expanded conjugated area and nitrogen atoms doping in polymer networks, the NTP displays extraordinary gas storage ability and excellent iodine adsorption capability.
引用
收藏
页码：1039 / 1043
页数：5
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