Microwave-enhanced formation of glucose from cellulosic waste

被引:35
作者
Fan, Jiajun [1 ]
De Bruyn, Mario [1 ]
Zhu, Zongyuan [1 ]
Budarin, Vitaliy [1 ]
Gronnow, Mark [1 ]
Gomez, Leonardo D. [1 ]
Macquarrie, Duncan [1 ]
Clark, James [1 ]
机构
[1] Univ York, Green Chem Ctr Excellence, Heslington YO10 5DD, N Yorkshire, England
关键词
Microwave; Biomass; Hydrothermal; Glucose; TECHNOLOGIES; HYDROLYSIS; SUGARS;
D O I
10.1016/j.cep.2013.01.004
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The conversion of cellulose and cellulosic waste to fermentable sugars has been successfully demonstrated. Using a novel microwave intensified hydrothermal depolymerisation of cellulosic materials in liquid hot water, at pressures below 300 psi, conversions of up to 40% of fermentable sugars were obtained with limited by-product formation. A high selectivity for glucose over other sugars has been observed. Temperature is the crucial parameter as limited conversion is observed below 180 degrees C and optimum conversion is attained around 220 degrees C. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:37 / 42
页数:6
相关论文
共 27 条
[1]   Release of monomeric sugars from Miscanthus sinensis by microwave-assisted ammonia and phosphoric acid treatments [J].
Boonmanumsin, P. ;
Treeboobpha, S. ;
Jeamjumnunja, K. ;
Luengnaruemitchai, A. ;
Chaisuwan, T. ;
Wongkasemjit, S. .
BIORESOURCE TECHNOLOGY, 2012, 103 (01) :425-431
[2]   NMR spectroscopy in the study of carbohydrates: Characterizing the structural complexity [J].
Bubb, WA .
CONCEPTS IN MAGNETIC RESONANCE PART A, 2003, 19A (01) :1-19
[3]   Use of green chemical technologies in an integrated biorefinery [J].
Budarin, Vitaly L. ;
Shuttleworth, Peter S. ;
Dodson, Jennifer R. ;
Hunt, Andrew J. ;
Lanigan, Brigid ;
Marriott, Ray ;
Milkowski, Kris J. ;
Wilson, Ashley J. ;
Breeden, Simon W. ;
Fan, Jiajun ;
Sin, Emily H. K. ;
Clark, James H. .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (02) :471-479
[4]   Microwave assisted decomposition of cellulose: A new thermochemical route for biomass exploitation [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Lanigan, Brigid A. ;
Shuttleworth, Peter ;
Macquarrie, Duncan J. .
BIORESOURCE TECHNOLOGY, 2010, 101 (10) :3776-3779
[5]   Cellulosic Biofuels [J].
Carroll, Andrew ;
Somerville, Chris .
ANNUAL REVIEW OF PLANT BIOLOGY, 2009, 60 :165-182
[6]   Eco-innovative design method for process engineering [J].
Ferrer, Jesus Barragan ;
Negny, Stephane ;
Cortes Robles, Guillermo ;
Le Lann, Jean Marc .
COMPUTERS & CHEMICAL ENGINEERING, 2012, 45 :137-151
[7]   Recovery of high added-value components from food wastes: Conventional, emerging technologies and commercialized applications [J].
Galanakis, Charis M. .
TRENDS IN FOOD SCIENCE & TECHNOLOGY, 2012, 26 (02) :68-87
[8]   Accessibility and size of Valonia cellulose microfibril studied by combined deuteration/rehydrogenation and FTIR technique [J].
Horikawa, Yoshiki ;
Sugiyama, Junji .
CELLULOSE, 2008, 15 (03) :419-424
[9]   Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering [J].
Huber, George W. ;
Iborra, Sara ;
Corma, Avelino .
CHEMICAL REVIEWS, 2006, 106 (09) :4044-4098
[10]   Controlled microwave heating in modern organic synthesis [J].
Kappe, CO .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) :6250-6284