What Remains Unexplained about the Properties of Halide Perovskites?

被引：248

作者：

Egger, David A. ^{[1
]}

Bera, Achintya ^{[2
]}

Cahen, David ^{[2
]}

Hodes, Gary ^{[2
]}

Kirchartz, Thomas ^{[3
,4
,5
]}

Kronik, Leeor ^{[2
]}

Lovrincic, Robert ^{[6
,7
]}

Rappe, Andrew M. ^{[8
]}

Reichman, David R. ^{[9
]}

Yaffe, Omer ^{[2
]}

机构：

[1] Univ Regensburg, Inst Theoret Phys, D-93040 Regensburg, Germany

[2] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel

[3] Forschungszentrum Julich, Photovolta IEK5, D-52425 Julich, Germany

[4] Univ Duisburg Essen, Fac Engn, D-47057 Duisburg, Germany

[5] Univ Duisburg Essen, CENIDE, D-47057 Duisburg, Germany

[6] InnovationLab, D-69115 Heidelberg, Germany

[7] TU Braunschweig, Inst High Frequency Technol, D-38106 Braunschweig, Germany

[8] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

[9] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

ADVANCED MATERIALS | 2018年 / 30卷 / 20期

关键词：

halide perovskites; optoelectronic properties; solar cells; METHYLAMMONIUM LEAD IODIDE; ORGANIC-INORGANIC PEROVSKITES; ORGANOMETAL TRIHALIDE PEROVSKITE; DEFECT-TOLERANT SEMICONDUCTORS; CHARGE-CARRIER LIFETIMES; SOLAR-CELLS; RADIATIVE RECOMBINATION; PHASE-TRANSITIONS; AMBIPOLAR TRANSPORT; OPTICAL PHONONS;

D O I：

10.1002/adma.201800691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The notion that halide perovskite crystals (ABX(3), where X is a halide) exhibit unique structural and optoelectronic behavior deserves serious scrutiny. After decades of steady and half a decade of intense research, the question which attributes of these materials are unusual, is discussed, with an emphasis on the identification of the most important remaining issues. The goal is to stimulate discussion rather than to merely present a community consensus.

引用

页数：11

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