Nitrogen-doped mesoporous carbon derived from biopolymer as electrode material for supercapacitors

被引:60
作者
Xu, Bin [1 ]
Hou, Shanshan [2 ]
Zhang, Fengling [2 ]
Cao, Gaoping [1 ]
Chu, Mo [2 ]
Yang, Yushang [1 ]
机构
[1] Res Inst Chem Def, Beijing 100191, Peoples R China
[2] China Univ Min & Technol Beijing, Sch Chem & Environm Engn, Beijing 100083, Peoples R China
基金
美国国家科学基金会;
关键词
Supercapacitor; Porous carbon; Nitrogen-doped; Capacitance; Rate performance; POROUS CARBON; PERFORMANCE; NANO-CACO3; TEMPLATE; GRAPHENE; STORAGE;
D O I
10.1016/j.jelechem.2013.11.020
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Nitrogen-doped mesoporous carbons were prepared using a biopolymer, gelatin as precursor by nano-CaCO3 template method. Although the surface area of the carbon obtained at 800 degrees C is only 666 m(2) g(-1), the existence of abundant nitrogen-containing functional groups with a nitrogen content of 10.72 wt% makes the carbon has a relative high capacitance of 198 F g(-1) in 6 mol L-1 KOH aqueous electrolytes. The developed mesoporous structure endows the carbon with good rate capability, and the capacitance can remain 135 F g(-1) even when the current density increases to 20 A g(-1.) The carbon also possesses excellent cycle durability, indicating an attractive electrode material for supercapacitors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:146 / 150
页数:5
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