The first example of anomeric glycoconjugation to phthalocyanines

被引：67
作者：
Alvarez-Mico, X [1 ]
Calvete, MJF [1 ]
Hanack, M [1 ]
Ziegler, T [1 ]
机构：
[1] Univ Tubingen, Inst Organ Chem 2, D-72076 Tubingen, Germany
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 19期
关键词：
carbohydrates; phthalocyanines; anomeric link;
D O I：
10.1016/j.tetlet.2006.03.029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Preparation and characterization of peripherally glucose substituted zinc(II) phthalocyanine 6, linked via the anomerie carbon through a novel glycosidation method is reported for the first time, for which classical Pc template chemistry with the unprotected phthalonitrile 4 could be used. Phthalocyanine 6 was formed in high yield and is displaying a high solubility in water as a primary condition for a potential biological application. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3283 / 3286
页数：4
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