Decomposition behavior and decomposition products of epoxy resin cured with MeHHPA in near-critical water

被引：6

作者：

Gong Xianyun ^{[1
,2
]}

Liu Yuyan ^{[1
]}

Jia Xuegang ^{[3
]}

Shan Guohua ^{[1
]}

机构：

[1] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China

[2] Harbin Univ, Dept Chem, Sch Sci, Harbin 150086, Peoples R China

[3] Misericordia Univ, Dept Chem & Biochem, Dallas, PA 18612 USA

来源：

JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2013年 / 28卷 / 04期

基金：

中国国家自然科学基金;

关键词：

epoxy resin; near-critical water; decomposition; mechanism; DEGRADATION;

D O I：

10.1007/s11595-013-0768-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A kind of chemical method that used water as the liquid reaction medium to decompose epoxy resin was studied. The thermosetting epoxy resin was decomposed successfully under the condition of near-critical water. The decomposition rate of epoxy resin raised rapidly as the reaction time and reaction temperature increased. The decomposition reaction products were characterized by infra-red spectra and gas chromatography-mass spectrometry. The phenol, isopropylphenol, 4, 4'-(1-methylethylidene) bis-phenol were found as the main compounds in liquid products, which were common monomers from epoxy resin. When reaction was carried out at the temperature of 260 A degrees C-300 A degrees C, the decomposition mechanism of epoxy resin was envisaged as the ether and ester bonds cracking.

引用

页码：781 / 786

页数：6

共 17 条

[1] Applications of high-temperature aqueous media for synthetic organic reactions [J].

An, JY ;

Bagnell, L ;

Cablewski, T ;

Strauss, CR ;

Trainor, RW .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (08) :2505-2511

[2] Chemical recycling of carbon fibers reinforced epoxy resin composites in oxygen in supercritical water [J].

Bai, Yongping ;

Wang, Zhi ;

Feng, Liqun .

MATERIALS & DESIGN, 2010, 31 (02) :999-1002

[3] Hydrogenolytic degradation of thermosets [J].

Braun, D ;

von Gentzkow, W ;

Rudolf, AP .

POLYMER DEGRADATION AND STABILITY, 2001, 74 (01) :25-32

[4] Near critical and supercritical water. Part I. Hydrolytic and hydrothermal processes [J].

Brunner, G. .

JOURNAL OF SUPERCRITICAL FLUIDS, 2009, 47 (03) :373-381

[5] Catalytic hydrolysis of waste nylon 6 to produce ε-caprolactam in sub-critical water [J].

Chen, Jinyang ;

Liu, Guiyang ;

Jin, Lujiang ;

Ni, Pei ;

Li, Zhi ;

He, Haibo ;

Xu, Yi ;

Zhang, Jianqiu ;

Dong, Junping .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2010, 87 (01) :50-55

[6] An approach to chemical recycling of epoxy resin cured with amine using nitric acid [J].

Dang, WR ;

Kubouchi, M ;

Yamamoto, S ;

Sembokuya, H ;

Tsuda, K .

POLYMER, 2002, 43 (10) :2953-2958

[7] Solvolysis of bisphenol A diglycidyl ether/anhydride model networks [J].

El Gersifi, K ;

Durand, G ;

Tersac, G .

POLYMER DEGRADATION AND STABILITY, 2006, 91 (04) :690-702

[8] Chemical recycling of plastics using sub- and supercritical fluids [J].

Goto, Motonobu .

JOURNAL OF SUPERCRITICAL FLUIDS, 2009, 47 (03) :500-507

[9] Thermal degradation of polystyrene wastes in various solvents [J].

Karaduman, A ;

Simsek, EH ;

Çiçek, B ;

Bilgesü, AY .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2002, 62 (02) :273-280

[10] Circulating flow reactor for recycling of carbon fiber from carbon fiber reinforced epoxy composite [J].

Lee, Seok-Ho ;

Choi, Hwan-Oh ;

Kim, Jung-Seok ;

Lee, Cheul-Kyu ;

Kim, Yong-Ki ;

Ju, Chang-Sik .

KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2011, 28 (02) :449-454

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