Efficient ruthenium-TEMPO-catalysed aerobic oxidation of aliphatic alcohols into aldehydes and ketones

被引：160

作者：

Dijksman, A ^{[1
]}

Arends, IWCE ^{[1
]}

Sheldon, RA ^{[1
]}

机构：

[1] Delft Univ Technol, Dept Biotechnol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a902594d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of RuCl2(PPh3)(3) and TEMPO affords an efficient catalytic system for the aerobic oxidation of a broad range of primary and secondary (aliphatic) alcohols at 100 degrees C, giving the corresponding aldehydes and ketones, respectively, in > 99% selectivity in all cases.

引用

页码：1591 / 1592

页数：2

共 34 条

[1] THE SELECTIVE OXIDATION OF PRIMARY ALCOHOLS TO ALDEHYDES BY O-2 EMPLOYING A TRINUCLEAR RUTHENIUM CARBOXYLATE CATALYST [J].

BILGRIEN, C ;

DAVIS, S ;

DRAGO, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3786-3787

[2]

Cainelli G., 1984, CHROMIUM OXIDATIONS

[3]

deNooy AEJ, 1996, SYNTHESIS-STUTTGART, P1153

[4] Chemoselective oxidation of alcohols to aldehydes and ketones by tert-butyl hydroperoxide catalyzed by a ruthenium complex of N,N′,N"-trimethyl-1,4,7-triazacyclononane [J].

Fung, WH ;

Yu, WY ;

Che, CM .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (09) :2873-2877

[5] OPTIMIZATION OF A SIMPLE SYSTEM FOR THE OXIDATION OF OCTAN-2-OL WITH SODIUM-BROMATE, MEDIATED BY RUTHENIUM TETRAOXIDE GENERATED INSITU [J].

GIDDINGS, S ;

MILLS, A .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (05) :1103-1107

[6] PREPARATION AND USE OF TETRA-NORMAL-BUTYLAMMONIUM PER-RUTHENATE (TBAP REAGENT) AND TETRA-NORMAL-PROPYLAMMONIUM PER-RUTHENATE (TPAP REAGENT) AS NEW CATALYTIC OXIDANTS FOR ALCOHOLS [J].

GRIFFITH, WP ;

LEY, SV ;

WHITCOMBE, GP ;

WHITE, AD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) :1625-1627

[7] Selective aerobic oxidation of primary alcohols catalyzed by a Ru(PPh3)3Cl2/hydroquinone system [J].

Hanyu, A ;

Takezawa, E ;

Sakaguchi, S ;

Ishii, Y .

TETRAHEDRON LETTERS, 1998, 39 (31) :5557-5560

[8]

Hinzen B, 1998, SYNTHESIS-STUTTGART, P977

[9]

HOLM R, 1970, INORG SYNTH, V12, P238

[10]

Hudlicky M., 1990, OXIDATIONS ORGANIC C

← 1 2 3 4 →