Efficient ruthenium-TEMPO-catalysed aerobic oxidation of aliphatic alcohols into aldehydes and ketones

被引：160
|
作者：
Dijksman, A [1 ]
Arends, IWCE [1 ]
Sheldon, RA [1 ]
机构：
[1] Delft Univ Technol, Dept Biotechnol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 16期
关键词：
D O I：
10.1039/a902594d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The combination of RuCl2(PPh3)(3) and TEMPO affords an efficient catalytic system for the aerobic oxidation of a broad range of primary and secondary (aliphatic) alcohols at 100 degrees C, giving the corresponding aldehydes and ketones, respectively, in > 99% selectivity in all cases.
引用
收藏
页码：1591 / 1592
页数：2
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