Efficient ruthenium-TEMPO-catalysed aerobic oxidation of aliphatic alcohols into aldehydes and ketones

被引：160

作者：

Dijksman, A ^{[1
]}

Arends, IWCE ^{[1
]}

Sheldon, RA ^{[1
]}

机构：

[1] Delft Univ Technol, Dept Biotechnol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a902594d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of RuCl2(PPh3)(3) and TEMPO affords an efficient catalytic system for the aerobic oxidation of a broad range of primary and secondary (aliphatic) alcohols at 100 degrees C, giving the corresponding aldehydes and ketones, respectively, in > 99% selectivity in all cases.

引用

页码：1591 / 1592

页数：2

共 34 条

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