A Simple Link between Hydrocarbon and Borohydride Chemistries

被引：53
|
作者：
Poater, Jordi [1 ,2 ]
Sola, Miquel [1 ,2 ]
Vinas, Clara [3 ]
Teixidor, Francesc [3 ]
机构：
[1] Univ Girona, Inst Quim Comp, Girona 17071, Catalonia, Spain
[2] Univ Girona, Dept Quim, Girona 17071, Catalonia, Spain
[3] CSIC, Inst Ciencia Dels Mat, Bellaterra 08193, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 13期
关键词：
boron; density functional calculations; hydrocarbons; multicentered bonds; sacrificial atoms; ELECTRON LOCALIZATION; DOUBLE-BOND; BORON; DELOCALIZATION; LIGAND; COMPLEXES; MOLECULES; REDUCTION; CLUSTERS; SYSTEMS;
D O I：
10.1002/chem.201204397
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A clear link between the hydrocarbon and borohydride chemistries is established by showing that hydrocarbons and borohydrides have a common root regulated by the number of valence electrons in a confined space. Application of the proposed method to archetypal hydrocarbons leads to well-known borohydrides but, more importantly, it allows the design of new and interesting boron-containing molecules that can be a source of inspiration for synthetic chemists.
引用
收藏
页码：4169 / 4175
页数：7
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