Self-assembly and guest binding of nickel(II) macrocyclic complex with pentyl groups and cis,cis-1,3,5-cyclohexanetricarboxylic acid

被引：1
|
作者：
Park, Ji Hye [1 ,2 ]
Jeong, Ah Rim [3 ]
Shin, Jong Won [3 ]
Jeong, Maeng Jun [3 ]
Cho, Chan Sik [4 ]
Min, Kil Sik [1 ,2 ]
机构：
[1] Kyungpook Natl Univ, Dept Chem Educ, Daegu 702701, South Korea
[2] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Daegu 702701, South Korea
[3] Kyungpook Natl Univ, Dept Chem, Daegu 702701, South Korea
[4] Kyungpook Natl Univ, Dept Appl Chem, Daegu 702701, South Korea
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 57卷
基金：
新加坡国家研究基金会;
关键词：
Macrocyclic ligand; Nickel(II); Crystal structure; Guest binding; Coordination polymer; METAL-ORGANIC FRAMEWORKS; COORDINATION; CATALYSIS; RECOGNITION; SOLIDS;
D O I：
10.1016/j.inoche.2015.04.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of the nickel(II) macrocyclic complex 1 including pendant pentyl groups in MeCN/H2O mixed solvent with deprotonated cis,cis-1,3,5-cyclohexanetricarboxylic acid (CTC3-) resulted in two-dimensional (2-D) coordination polymer [Ni(C18H42N6)](3)[C6H9(COO)(3)](2)center dot 6H(2)O center dot 6CH(3)CN (2). The crystal structure of 2 indicates that each nickel(II) macrocyclic unit binds two CTC3- ions in trans position and each CTC3- ion coordinates three nickel(II) macrocyclic complexes to form a 2-D layer with hexagonal motif. The dried solid of 2 differentiates MeOH, EtOH, and PhOH in toluene solvent with the K-f values of 138, 2.11, and 6.68 M-1, respectively. (C) 2015 Elsevier B.V. All rights reserved.
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页码：44 / 46
页数：3
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