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An Electrochemical Sensor for Analysis of Food Red 17 in the Presence of Tartrazine in Food Products Amplified with CdO/rGO Nanocomposite and 1,3-Dipropylimidazolium Bromide
被引:27
作者:
Misaghpour, Fahimeh
[1
]
Shabani-Nooshabadi, Mehdi
[1
]
机构:
[1] Univ Kashan, Dept Analyt Chem, Fac Chem, Kashan, Iran
关键词:
Carbon paste electrode;
CdO nanoparticle decorated onto graphene nanosheet;
1,3-Dipropylimidazolium bromide;
Food Red 17;
CARBON-PASTE ELECTRODE;
DIFFERENTIAL-PULSE POLAROGRAPHY;
SENSITIVE VOLTAMMETRIC SENSOR;
SOLID-PHASE EXTRACTION;
IONIC LIQUID;
ALLURA RED;
ASCORBIC-ACID;
SOFT DRINKS;
PONCEAU;
4R;
SUDAN I;
D O I:
10.1007/s12161-017-1035-7
中图分类号:
TS2 [食品工业];
学科分类号:
0832 ;
摘要:
Carbon paste electrode amplified with CdO nanoparticle (spherical shape) decorated onto graphene nanosheet and 1,3-dipropylimidazolium bromide (CdO-NP/rGO/1,3-DPZBr/CPE) was fabricated and suggested as an electrochemical sensor for analysis of Food Red 17 in the presence of tartrazine. At pH 3.0 as best condition, the electrooxidation wave of a potential 850 mV was observed for Food Red 17. On the other hand, due to high conductivity of 1,3-DPZBr and large surface area of CdO-NP/rGO, we detect a high oxidation sensitivity for analysis of Food Red 17. The CdO-NP/rGO/1,3-DPZBr/CPE showed a good ability for resolving of Food Red 17 and tartrazine oxidation signals as two important dye colors. As a result, we found dynamic range of 4.0 nM-8.0 mu M with detection limit 1.0 nM for analysis of Food Red 17 at a surface of the CdO-NP/rGO/1,3-DPZBr/CPE. The CdO-NP/rGO/1,3-DPZBr/CPE was used for analysis of Food Red 17 in washing liquid, ice cream, and jelly powder samples.
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页码:646 / 653
页数:8
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