Selective chemical reactions in supercritical carbon dioxide, water, and ionic liquids

被引：45
作者：
Skouta, Rachid [1 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
来源：
GREEN CHEMISTRY LETTERS AND REVIEWS | 2009年 / 2卷 / 03期
关键词：
alternative "green" solvents; water; ionic liquids; supercritical carbon dioxide; transition metals; CATALYZED ASYMMETRIC HYDROGENATION; OPENING METATHESIS POLYMERIZATION; CROSS-COUPLING REACTIONS; ELECTRON-RICH OLEFINS; HECK REACTION; ORGANIC-REACTIONS; IN-SITU; HOMOGENEOUS CATALYSIS; HIGHLY EFFICIENT; ENANTIOSELECTIVE HYDROGENATION;
D O I：
10.1080/17518250903230001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alternative solvents such as supercritical carbon dioxide, water, and ionic liquids are receiving an increase of interest as better replacements for conventional solvents in chemical reactions. They have been called sustainable green solvents because they are highly promising reaction mediums for organic synthesis. This review presents an overview of some selected chemical reactions that have been developed in these green solvents with a particular emphasis on metal-catalyzed reactions.
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页码：121 / 156
页数：36
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