Growth of sillenite-structure single crystals

被引:39
作者
Skorikov, VM
Kargin, YF
Egorysheva, AV
Volkov, VV
Gospodinov, M
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[2] Bulgarian Acad Sci, Inst Solid State Phys, Sofia 1784, Bulgaria
关键词
D O I
10.1007/s10789-005-0317-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The main processes for preparing bulk single crystals and films of photorefractive and piezoelectric Bi12MxO20 +/-delta (M = Group II-VIII elements) sillenite compounds are considered. Experimental data are summarized on the crystal growth of Bi12MxO20 +/-delta from the melt and under hydrothermal conditions, and the key morphological features of sillenites are analyzed. Various types of macroscopic growth defects in sillenite-type crystals are described, and their origin is discussed. The compositions of second-phase inclusions in undoped and doped (Group I-VIII elements) Bi12SiO20, Bi12GeO20, and Bi12TiO20 single crystals are presented, and the main physicochemical properties of various Bi12MxO20 +/-delta crystals are summarized.
引用
收藏
页码:S24 / S46
页数:23
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