A NbO type Cu(II) metal-organic framework showing efficient catalytic activity in the Friedlander and Henry reactions

被引：45

作者：

Gupta, Anoop K. ^{[1
]}

De, Dinesh ^{[1
]}

Bharadwaj, Parimal K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, UP, India

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 24期

关键词：

SOLVENT-FREE CONDITIONS; COORDINATION POLYMERS; QUINOLINE DERIVATIVES; HETEROGENEOUS CATALYSIS; CONJUGATED POLYMERS; GAS-ADSORPTION; LEWIS ACIDITY; LIGAND; SITES; MOFS;

D O I：

10.1039/c7dt01595j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A three-dimensional NbO type porous metal-organic framework 1 containing both tertiary amine groups and paddle wheel dinuclear Cu-2(COO)(4) secondary building units as the active centre was synthesized at room temperature. The activated framework 1' can be used as an efficient heterogeneous catalyst for the synthesis of quinoline derivatives by the Friedlander reaction and for the synthesis of beta-nitroalcohols by the Henry (nitroaldol) reaction. This MOF-based heterogeneous catalyst is easily recycled and reused further without losing its structural integrity and catalytic activity.

引用

页码：7782 / 7790

页数：9

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