Unsymmetric Electronic Push-Pull Bipyrroles - Synthesis, Spectroelectrochemical, and Photophysical Investigation

被引：22
|
作者：
Tshibaka, Tshitundu
Roche, Ivan Ulliel [1 ]
Dufresne, Stephane [1 ]
Lubell, William D. [1 ]
Skene, W. G. [1 ]
机构：
[1] Univ Montreal, Dept Chim, Ctr Self Assembled Chem Struct, Montreal, PQ H3C 3J7, Canada
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 24期
基金：
加拿大创新基金会; 加拿大自然科学与工程研究理事会;
关键词：
ELECTROCHEMICAL PROPERTIES; AZOMETHINE CONNECTIONS; PYRROLE; POLYMERS; PRODIGIOSIN; THIOPHENE; FACILE; 2,2'-BIPYRROLES; OLIGOPYRROLES; GENERATION;
D O I：
10.1021/jo901965t
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The electrochromic and photophysical behaviors of unsymmetric bipyrroles were observed its intense color changes of the oxidized products relative to the neutral form. The color of the oxidized form and the oxidation potential were both tunable contingent on electronic group and substitution.
引用
收藏
页码：9497 / 9500
页数：4
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