Abatement of NO Using Rhodium Catalysts Supported on Carbon Nanotubes: Carbon as Support Material and Reducing Agent

被引:17
作者
Beyer, Hans [1 ]
Chatziapostolou, Konstantinos [1 ]
Koehler, Klaus [1 ]
机构
[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany
关键词
NO; Decomposition; Reduction; Rhodium catalyst; CNT; NITRIC-OXIDE; DECOMPOSITION; KINETICS; RH(111);
D O I
10.1007/s11244-009-9340-z
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The catalytic abatement of NO over rhodium catalysts supported on carbon nanotubes was studied. In the absence of oxygen, Rh/carbon nanotubes (CNT) catalysts exhibit high activities in the catalytic reduction of NO with the carbon support acting as the reducing agent. The lifetime of the catalysts is limited by the stoichiometric oxidation of the support material.
引用
收藏
页码:1752 / 1756
页数:5
相关论文
共 20 条
  • [1] Isothermal kinetic study of the decomposition of nitric oxide over Rh(111) surfaces
    Aryafar, M
    Zaera, F
    [J]. JOURNAL OF CATALYSIS, 1998, 175 (02) : 316 - 327
  • [2] Carbons as supports for industrial precious metal catalysts
    Auer, E
    Freund, A
    Pietsch, J
    Tacke, T
    [J]. APPLIED CATALYSIS A-GENERAL, 1998, 173 (02) : 259 - 271
  • [3] COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS
    BETHUNE, DS
    KIANG, CH
    DEVRIES, MS
    GORMAN, G
    SAVOY, R
    VAZQUEZ, J
    BEYERS, R
    [J]. NATURE, 1993, 363 (6430) : 605 - 607
  • [4] THE DISSOCIATION KINETICS OF NO ON RH(III) AS STUDIED BY TEMPERATURE-PROGRAMMED STATIC SECONDARY-ION MASS-SPECTROMETRY AND DESORPTION
    BORG, HJ
    REIJERSE, JFCJM
    VANSANTEN, RA
    NIEMANTSVERDRIET, JW
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (11) : 10052 - 10063
  • [5] Fullerene-based materials as new support media in heterogeneous catalysis by metals
    Coq, B
    Planeix, JM
    Brotons, V
    [J]. APPLIED CATALYSIS A-GENERAL, 1998, 173 (02) : 175 - 183
  • [6] Synthesis of supported catalysts
    de Jong, KP
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1999, 4 (01) : 55 - 62
  • [7] Carbon nanofibers: Catalytic synthesis and applications
    De Jong, KP
    Geus, JW
    [J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2000, 42 (04): : 481 - 510
  • [8] NO+CO+O2 reaction kinetics on Rh(111):: A molecular beam study
    Gopinath, CS
    Zaera, F
    [J]. JOURNAL OF CATALYSIS, 2001, 200 (02) : 270 - 287
  • [9] Selective catalytic reduction of NO by propane over CoOx/Al2O3:: an investigation of the surface reactions using in situ infrared spectroscopy
    He, CH
    Kölher, K
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (07) : 898 - 905
  • [10] SINGLE-SHELL CARBON NANOTUBES OF 1-NM DIAMETER
    IIJIMA, S
    ICHIHASHI, T
    [J]. NATURE, 1993, 363 (6430) : 603 - 605