Delineation of the Critical Parameters of Salt Catalysts in the N-Formylation of Amines with CO2

被引：27

作者：

Hulla, Martin ^{[1
]}

Ortiz, Daniel ^{[1
]}

Katsyuba, Sergey ^{[2
]}

Vasilyev, Dmitry ^{[1
]}

Dyson, Paul J. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chem & Chem Engn, CH-1015 Lausanne, Switzerland

[2] RAS, FRC, Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, Arbuzov St 8, Kazan 420088, Russia

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 47期

关键词：

base catalysis; carbon dioxide; hydrosilanes; ion pairing; sustainable chemistry; CARBON-DIOXIDE; IONIC LIQUIDS; REDUCTIVE FUNCTIONALIZATION; FLUORIDE; KETONES; HYDROSILANES; HYDROSILYLATION; METHYLATION; FORMAMIDES; ACTIVATION;

D O I：

10.1002/chem.201901686

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-formylation of amines with CO2 is base-catalyzed and studies of salt catalysts reveal that the reaction is efficiently catalyzed by "free" floating anions of high basicity, as represented in the cover image. More information can be found in the Full Paper by P. J. Dyson et al. (DOI: 10.1002/chem.201901686).

引用

页码：11074 / 11079

页数：6

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