Preparation, characterization and X-ray structures of 1-methylisatin 3-thiosemicarbazone copper, nickel and cobalt complexes

被引：59

作者：

Ferrari, MB ^{[1
]}

Pelizzi, C

Pelosi, G

Rodríguez-Argüelles, MC

机构：

[1] Univ Parma, Dipartimento Chim Gen& Inorgan Chim Analit, I-43100 Parma, Italy

[2] Univ Vigo, Dept Quim Inorgan, Vigo 36200, Spain

来源：

POLYHEDRON | 2002年 / 21卷 / 25-26期

关键词：

X-ray; thiosemicarbazone; isatin; metal complexes;

D O I：

10.1016/S0277-5387(02)01234-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper, nickel and cobalt complexes of 1-methylisatin 3-thiosemicarbazone (HL) have been synthesized and characterized by means of spectroscopic techniques. The X-ray crystal structures of [CuClL](n) (1), [NiL2] (2), [CoL2]2[CoCl4](.)2EtOH (3) were also determined. In all compounds the monodeprotonated ligand behaves as O, N, S terdentate. In the copper complex the coordination geometry is square-pyramidal with the ligand and a chlorine atom lying on the basal plane; a bridging sulphur atom in axial position forms polymeric chains. The nickel atom of complex 2 is surrounded by six donor atoms of two ligand moieties in a distorted octahedral fashion. The molecular structure of compound 3 consists of octahedral [CoL2](+) cations, [CoCl4](2-) anions and solvate ethanol molecules. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2593 / 2599

页数：7

共 23 条

[11] THIOSEMICARBAZONES AS COORDINATING AGENTS .3. SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, AND X-RAY STRUCTURE OF METHYL PYRUVATE THIOSEMICARBAZONE HEMIHYDRATE, CHLORO(ETHYL PYRUVATE THIOSEMICARBAZONATO)COPPER(II) (GREEN FORM), AND CHLORO(PYRUVIC ACID THIOSEMICARBAZONATO)COPPER(II) DIHYDRATE (BLUE FORM) [J].

FERRARI, MB ;

FAVA, GG ;

TARASCONI, P ;

PELIZZI, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (02) :361-366

[12] SYNTHESIS, SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION, AND BIOLOGICAL-ACTIVITY OF AQUACHLORO(PYRIDOXAL THIOSEMICARBAZONE) COPPER(II) CHLORIDE [J].

FERRARI, MB ;

FAVA, GG ;

TARASCONI, P ;

ALBERTINI, R ;

PINELLI, S ;

STARCICH, R .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1994, 53 (01) :13-25

[13]

Johnson C. K, 1996, ORNL6895

[14] Spectral and structural studies of metal complexes of isatin 3-hexamethyleneiminylthiosemicarbazone prepared electrochemically [J].

Labisbal, E ;

Sousa, A ;

Castiñeiras, A ;

García-Vázquez, JA ;

Romero, J ;

West, DX .

POLYHEDRON, 2000, 19 (10) :1255-1262

[15]

Labisbal E, 2000, Z NATURFORSCH B, V55, P162

[16]

Nardelli M., 1995, J APPL CRYSTALLOGR, V28, P659, DOI [10.1107/S0021889895007138, DOI 10.1107/S0021889895007138]

[17]

PANDEYA SN, 1993, PHARMAZIE, V48, P659

[18] Synthesis, antibacterial, antifungal and anti-HIV activities of Schiff and Mannich bases derived from isatin derivatives and N-[4-(4′-chlorophenyl)thiazol-2-yl] thiosemicarbazide [J].

Pandeya, SN ;

Sriram, D ;

Nath, G ;

DeClercq, E .

EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES, 1999, 9 (01) :25-31

[19] Transition-metal complexes of isatin-β-thiosemicarbazone.: X-ray crystal structure of two nickel complexes [J].

Rodríguez-Argüelles, MC ;

Sánchez, A ;

Ferrari, MB ;

Fava, GG ;

Pelizzi, C ;

Pelosi, G ;

Albertini, R ;

Lunghi, P ;

Pinelli, S .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 73 (1-2) :7-15

[20] Acenaphthenequinone thiosemicarbazone and its transition metal complexes: Synthesis, structure, and biological activity [J].

RodriguezArguelles, MC ;

Ferrari, MB ;

Fava, GG ;

Pelizzi, C ;

Pelosi, G ;

Albertini, R ;

Bonati, A ;

DallAglio, PP ;

Lunghi, P ;

Pinelli, S .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1997, 66 (01) :7-17

← 1 2 3 →