Synthesis and Structures of Mononuclear Co(III) and Cu(II) Complexes Derived from N-[2-(2-Hydroxy-3-methoxybenzylideneamino) cyclohexyl]-2-hydroxybenzamide

被引:0
作者
Wang, Hui-Yu [1 ]
Li, Yun-Hui [1 ]
Ma, Yu-Qin [1 ]
Gao, Ying [1 ]
Yu, Gui-Miao [1 ]
Yang, Xiu-Yun [1 ]
机构
[1] Changchun Univ Sci & Technol, Sch Chem & Environm Engn, Changchun 130022, Peoples R China
关键词
Cobalt(II); Copper(II); Complexes; Crystal structure; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; PROPERTY; BEHAVIOR;
D O I
10.14233/ajchem.2014.15501
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two mononuclear complexes, [Co(HL)(2)(C8H7O3)]center dot(CH3OH)(2) (1) and [Cu(HL)(2)] (2) where H2L = N-[2-(2-hydroxy-3-methoxybenzylideneamino) cyclohexyl]-2-hydroxybenzamide have been synthesized and characterized by IR, elemental analysis and crystal structure analysis. In complexes (1) and (2) the core ion has the six-coordinated N2O4 environment with a distorted octahedral geometry and four-coordinated N2O2 environment with a distorted square-planar geometry, respectively.
引用
收藏
页码:733 / 735
页数:3
相关论文
共 22 条
  • [1] {4-chloro-2′-[(3-methoxy-2-oxidophenyl)-methylidene]benzohydrazido}(pyridine)copper(II)
    Ali, H
    Khamis, NA
    Basirun, WJ
    Yamin, BM
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M982 - M983
  • [2] A trinuclear gadolinium complex:: Structure and magnetic properties
    Costes, JP
    Dahan, F
    Nicodème, F
    [J]. INORGANIC CHEMISTRY, 2001, 40 (20) : 5285 - +
  • [3] Crystal structures and magnetic properties of (2,2′-dipyridyl)-(3-methoxysalicylaldiminato)copper(II) perchlorate and (2,2′-dipyridyl)-(4-methoxysalicylaldiminato)copper(II) perchlorate
    Elerman, Y
    Elmali, A
    Svoboda, I
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2002, 57 (05): : 519 - 523
  • [4] Elmali A, 2000, ACTA CRYSTALLOGR C, V56, P423
  • [5] Synthetic aspects, crystal structure and antibacterial activity of two new Schiff base cobalt(III) complexes
    Fleck, Michel
    Karmakar, Debasis
    Ghosh, Mahendra
    Ghosh, Anupam
    Saha, Rajat
    Bandyopadhyay, Debasis
    [J]. POLYHEDRON, 2012, 34 (01) : 157 - 162
  • [6] Synthesis and magnetic property of copper(II)-lanthanide(III) complexes [{CuIILLnIII(o-van)(CH3COO)(MeOH)}2]•2H2O (LnIII = GdIII, TbIII, and DyIII;: H3L=1-(2-hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane;: o-van=3-methoxysalicylaldehydato)
    Hamamatsu, Takefumi
    Yabe, Kazuya
    Towatari, Masaaki
    Matsumoto, Naohide
    Re, Nazzareno
    Pochaba, Andrzej
    Mrozinski, Jerzy
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (03) : 523 - 529
  • [7] Crystal structures and magnetic properties of tetranuclear copper(II) complexes of N-(2-hydroxymethylphenyl)salicylideneimine with a defective double-cubane core
    Koikawa, M
    Yamashita, H
    Tokii, T
    [J]. INORGANICA CHIMICA ACTA, 2004, 357 (09) : 2635 - 2642
  • [8] Five Metal(II) Coordination Polymers Constructed from Two Vanillin Derivatives: From Discrete Structure to 3D Diamondoid Network
    Li, Shou-Hu
    Gao, Shao-Kang
    Liu, Shi-Xiong
    Guo, Yun-Nan
    [J]. CRYSTAL GROWTH & DESIGN, 2010, 10 (02) : 495 - 503
  • [9] Geometric Selectivity, Hydrogen-Bonding Interaction, and Solvatochromism of Bis{N-(aminoalkyl)salicylamidato(2-)}cobaltate(III)
    Mitsuhashi, Ryoji
    Suzuki, Takayoshi
    Sunatsuki, Yukinari
    Kojima, Masaaki
    [J]. CHEMISTRY LETTERS, 2011, 40 (07) : 696 - 698
  • [10] Synthesis and characterization of new addition compounds of bis(substituted-salicylaldeh.ydo) cobalt(II) with 2,2′-bipyridine (bipy).: Crystal and molecular structures of [CoII(3-methoxy-salicylaldehyde)2(bipy)] • CH3OH (1) and [CoII(bipy)3]Br2 • 0.5(5-chloro-salicylaldehydeH) • 1.5CH3OH (5)
    Papadopoulos, Christos D.
    Hatzidimitriou, Antonios G.
    Voutsas, George P.
    Lalia-Kantouri, Maria
    [J]. POLYHEDRON, 2007, 26 (05) : 1077 - 1086