Taguchi optimized synthesis of graphene films by copper catalyzed ethanol decomposition

被引：27

作者：

Santangelo, S. ^{[1
]}

Messina, G. ^{[2
]}

Malara, A. ^{[2
]}

Lisi, N. ^{[3
]}

Dikonimos, T. ^{[3
]}

Capasso, A. ^{[3
]}

Ortolani, L. ^{[4
]}

Morandi, V. ^{[4
]}

Faggio, G. ^{[2
]}

机构：

[1] Mediterranea Univ, Dept Civil Engn Energy Environm & Mat, DICEAM, I-89122 Reggio Di Calabria, Italy

[2] Mediterranea Univ, Dept Informat Infrastruct & Sustainable Energy, DIIES, I-89122 Reggio Di Calabria, Italy

[3] ENEA, Casaccia Res Ctr, Mat Technol Unit, Surface Technol Lab, I-00123 Rome, Italy

[4] CNR IMM Bologna, I-40129 Bologna, Italy

来源：

关键词：

Graphene; Taguchi method; Raman spectroscopy; Chemical vapor deposition; CHEMICAL-VAPOR-DEPOSITION; LARGE-AREA; GROWTH; DESIGN; PARAMETERS;

D O I：

10.1016/j.diamond.2013.11.006

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Taguchi method is for the first time applied to optimize the synthesis of graphene films by copper-catalyzed decomposition of ethanol. In order to find the most appropriate experimental conditions for the realization of thin high-grade films, six experiments suitably designed and performed. The influence of temperature (1000-1070 degrees C) and synthesis duration (1-30 min) and hydrogen flow (0-100 sccm) on the number of graphene layers and defect density in the graphitic lattice was ranked by monitoring the intensity of the 2D-and D-bands relative to the G-band in the Raman spectra. After critical examination and adjusting of the conditions predicted to give optimal results, a continuous film consisting of 2-4 nearly defect-free graphene layers was obtained. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：73 / 78

页数：6

共 28 条

[1] Optimisation of the new time-modulated CVD process using the Taguchi method [J].

Ali, N ;

Neto, F ;

Mei, S ;

Cabral, G ;

Kousar, Y ;

Titus, E ;

Ogwu, AA ;

Misra, DS ;

Gracio, J .

THIN SOLID FILMS, 2004, 469 (SPEC. ISS.) :154-160

[2] An overview of graphene in energy production and storage applications [J].

Brownson, Dale A. C. ;

Kampouris, Dimitrios K. ;

Banks, Craig E. .

JOURNAL OF POWER SOURCES, 2011, 196 (11) :4873-4885

[3] Observations of Early Stage Graphene Growth on Copper [J].

Celebi, K. ;

Cole, M. T. ;

Teo, K. B. K. ;

Park, H. G. .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2012, 15 (01) :K1-K4

[4] Fabrication optimisation of carbon fiber electrode with Taguchi method [J].

Cheng, CC ;

Young, MS ;

Chuang, CL ;

Chang, CC .

BIOSENSORS & BIOELECTRONICS, 2003, 18 (07) :847-855

[5] Growth of large-sized graphene thin-films by liquid precursor-based chemical vapor deposition under atmospheric pressure [J].

Dong, Xiaochen ;

Wang, Peng ;

Fang, Wenjing ;

Su, Ching-Yuan ;

Chen, Yu-Hsin ;

Li, Lain-Jong ;

Huang, Wei ;

Chen, Peng .

CARBON, 2011, 49 (11) :3672-3678

[6] Raman spectrum of graphene and graphene layers [J].

Ferrari, A. C. ;

Meyer, J. C. ;

Scardaci, V. ;

Casiraghi, C. ;

Lazzeri, M. ;

Mauri, F. ;

Piscanec, S. ;

Jiang, D. ;

Novoselov, K. S. ;

Roth, S. ;

Geim, A. K. .

PHYSICAL REVIEW LETTERS, 2006, 97 (18)

[7] Robust design of head interconnect for hard disk drive [J].

Gao, XK ;

Liu, QH ;

Liu, ZJ .

JOURNAL OF APPLIED PHYSICS, 2005, 97 (10)

[8] The rise of graphene [J].

Geim, A. K. ;

Novoselov, K. S. .

NATURE MATERIALS, 2007, 6 (03) :183-191

[9] Graphene: Status and Prospects [J].

Geim, A. K. .

SCIENCE, 2009, 324 (5934) :1530-1534

[10] Chemical vapor deposition synthesis of graphene on copper with methanol, ethanol, and propanol precursors [J].

Guermoune, Abdeladim ;

Chari, Tarun ;

Popescu, Filip ;

Sabri, Shadi S. ;

Guillemette, Jonathan ;

Skulason, Helgi S. ;

Szkopek, Thomas ;

Siaj, Mohamed .

CARBON, 2011, 49 (13) :4204-4210

← 1 2 3 →