Raman Spectroscopy of SiO2-Na2O-Al2O3-B2O3 glass doped with Nd3+ and CdS nanocrystals

被引:28
作者
Serqueira, E. O. [1 ]
Dantas, N. O. [1 ]
Anjos, V. [2 ]
Bell, M. J. V. [2 ]
机构
[1] Univ Fed Uberlandia, LNMIS, Inst Fis, BR-38400902 Uberlandia, MG, Brazil
[2] ICE UFJF, Grp Espectroscopia Mat, Dept Fis, BR-36036330 Juiz De Fora, MG, Brazil
关键词
Raman; Glasses; Semiconductor quantum dots; Rare earth ions; SILICATE-GLASSES; SCATTERING; SPECTRA; SIGNATURES; IONS;
D O I
10.1016/j.jallcom.2013.08.108
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the Raman spectroscopic characterization of a SNAB glass system doped with neodymium and CdS nanocrystals and fabricated by the fusion process. Raman spectra revealed CdS nanocrystals in the glass host and bands associated with Si-O vibrational modes with five structural configurations, boroxol modes of B2O3, Al-O and Cd-S vibrational modes. Additionally, Nd2O3 modifies the growth of CdS nanocrystals in the SNAB glass and Nd3+ ions are not incorporated inside the semiconductor nanocrystals. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:730 / 733
页数:4
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