Solid base catalysts obtained from hydrotalcite precursors, for Knoevenagel synthesis of cinamic acid and coumarin derivatives

被引：48
作者：
Angelescu, E.
Pavel, O. D.
Birjega, R.
Zavoianu, R.
Costentin, G.
Che, M.
机构：
[1] Univ Bucharest, Fac Chem, Dept Chem Technol & Catalysis, Bucharest 030018, Romania
[2] SC ZECASIN SA, Bucharest, Romania
[3] Univ Paris 06, UMR 7609, Lab Reactiv Surface, F-75252 Paris 05, France
来源：
APPLIED CATALYSIS A-GENERAL | 2006年 / 308卷
关键词：
calcined hydrotalcites; solid base catalysts for cinamic acid and coumarin derivatives synthesis;
D O I：
10.1016/j.apcata.2006.04.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The goal of this paper was to study the synthesis of the cinamic acid, coumarin-3-carboxilic acid and their ethylesters by Knoevenagel condensation using the solid base catalysts obtained from calcined Mg-Al, Mg-Al + Ln (Ln = Dy, Gd) and Li-Al hydrotalcites, under solvent free conditions. Correlations between the basicity of the catalysts and the advancement degree in the pathway of the condensation reaction have also been investigated. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：13 / 18
页数：6
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