Denitrogenative Transformations of Pyridotriazoles and Related Compounds: Synthesis of N-Containing Heterocyclic Compounds and Beyond

被引：89

作者：

Yadagiri, Dongari ^{[1
]}

Rivas, Monica ^{[1
]}

Gevorgyan, Vladimir ^{[1
]}

机构：

[1] Univ Texas Dallas, Dept Chem & Biochem, Richardson, TX 75080 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 85卷 / 17期

基金：

美国国家科学基金会;

关键词：

ONE-POT SYNTHESIS; RH-CATALYZED TRANSANNULATION; EFFICIENT SYNTHESIS; OXIDATION-STATE; TRIAZOLOPYRIDINES; REARRANGEMENTS; ESTERS; CYCLOPROPENES; INDOLIZIDINE; CYCLIZATION;

D O I：

10.1021/acs.joc.0c01652

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The high demand for new and efficient routes toward synthesis of nitrogen-containing heterocyclic scaffolds has inspired organic chemists to discover several methodologies over recent years. This Perspective highlights one standout approach, which involves the use of pyridotriazoles and related compounds in denitrogenative transformations. Readily available pyridotriazoles undergo ring-chain isomerization to produce uniquely reactive alpha-diazoimines. Such reactivity, enabled by metal catalysts, additives, or visible-light irradiation, can be applied in transannulation, insertion, cyclopropanation, and many other transformations.

引用

页码：11030 / 11046

页数：17

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