An Efficient Synthesis of Dibenzo[b,f]oxepins by Ring-Closing Metathesis

被引:15
作者
Bharath, Yada [1 ]
Thirupathi, Barla [1 ]
Ranjit, Gurram [1 ]
Mohapatra, Debendra K. [1 ]
机构
[1] Indian Inst Chem Technol, CSIR, Nat Prod Chem Div, Hyderabad 500007, Andhra Pradesh, India
关键词
Bauhinia; dibenzo[b; f]oxepins; 2,2 '-oxybis(vinylbenzenes); ring-closing metathesis; Ullmann reaction; ULLMANN-TYPE SYNTHESIS; 1ST TOTAL-SYNTHESIS; DIARYL ETHERS; ARYL IODIDES; C-N; COPPER; DERIVATIVES; ARTOCARPOL; CATALYSTS; PHENOLS;
D O I
10.1002/ajoc.201300141
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dibenzo[b,f]oxepin scaffolds, which have been found in the Bauhinia plant family and have potent medicinal properties, have been prepared efficiently by a two-step protocol that involves Ullmann-type coupling and ring-closing metathesis reactions.
引用
收藏
页码:848 / 851
页数:4
相关论文
共 50 条
  • [21] Ring-Closing Metathesis in Aqueous Micellar Medium
    Laville, Lionel
    Charnay, Clarence
    Lamaty, Frederic
    Martinez, Jean
    Colacino, Evelina
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (03) : 760 - 764
  • [22] Ring-closing metathesis for the synthesis of heteroaromatics: evaluating routes to pyridines and pyridazines
    Donohoe, Timothy J.
    Bower, John F.
    Basutto, Jose A.
    Fishlock, Lisa P.
    Procopiou, Panayiotis A.
    Callens, Cedric K. A.
    TETRAHEDRON, 2009, 65 (44) : 8969 - 8980
  • [23] Synthesis of oxa-cage compounds by ketalization and ring-closing metathesis
    Kotha, Sambasivarao
    Ansari, Saima
    Cheekatla, Subba Rao
    Dipak, Mirtunjay Kumar
    TETRAHEDRON, 2020, 76 (05)
  • [24] Synthesis of spiro carba-sugars by ring-closing metathesis
    González-Bello, C
    Castedo, L
    Cañada, FJ
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (04) : 1002 - 1011
  • [25] Ring-closing olefin metathesis for the synthesis of phosphorus containing heterocycles
    Hetherington, L
    Greedy, B
    Gouverneur, V
    TETRAHEDRON, 2000, 56 (14) : 2053 - 2060
  • [26] A Ring-Closing Metathesis-Based Approach to the Synthesis of (±)-Tetrabenazine
    Johannes, Manuel
    Altmann, Karl-Heinz
    ORGANIC LETTERS, 2012, 14 (14) : 3752 - 3755
  • [27] Ring-closing metathesis protocol for a diastereocontrolled synthesis of (-)-shikimic acid
    Takeuchi, M
    Taniguchi, T
    Ogasawara, K
    SYNTHESIS-STUTTGART, 2000, (10): : 1375 - 1379
  • [28] Ring-closing metathesis mediated synthesis of pyrrolizidine and quinolizidine azasugars
    Overkleeft, HS
    Bruggeman, P
    Pandit, UK
    TETRAHEDRON LETTERS, 1998, 39 (22) : 3869 - 3872
  • [29] Recent applications of ring-closing metathesis in the synthesis of lactams and macrolactams
    Hassan, Hani Mutlak A.
    CHEMICAL COMMUNICATIONS, 2010, 46 (48) : 9100 - 9106
  • [30] Ring-Closing Enyne Metathesis (RCEYM) for the Synthesis of Cyclic Sulfoximines
    Fueger, Bernhard
    Bolm, Carsten
    SYNLETT, 2009, (10) : 1601 - 1604