A review of catalytic hydrodeoxygenation of lignin-derived phenols from biomass pyrolysis

被引：456

作者：

Bu, Quan ^{[1
]}

Lei, Hanwu ^{[1
]}

Zacher, Alan H. ^{[2
]}

Wang, Lu ^{[1
]}

Ren, Shoujie ^{[1
]}

Liang, Jing ^{[1
]}

Wei, Yi ^{[1
]}

Liu, Yupeng ^{[1
]}

Tang, Juming ^{[1
]}

Zhang, Qin ^{[1
]}

Ruan, Roger ^{[3
]}

机构：

[1] Washington State Univ, Dept Biol Syst Engn, Bioprod Sci & Engn Lab, Richland, WA 99354 USA

[2] Pacific NW Natl Lab, Richland, WA 99354 USA

[3] Univ Minnesota, Dept Bioprod & Biosyst Engn, St Paul, MN 55108 USA

来源：

BIORESOURCE TECHNOLOGY | 2012年 / 124卷

关键词：

Lignin-derived phenols; Catalytic hydrodeoxygenation (HDO); Pyrolysis; Mechanism; Kinetics; BIO-OIL; TRANSPORTATION FUELS; MODEL COMPOUNDS; HYDROGEN; DEACTIVATION; CONVERSION; KINETICS; RESIDUE; HDO;

D O I：

10.1016/j.biortech.2012.08.089

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Catalytic hydrodeoxygenation (HDO) of lignin-derived phenols which are the lowest reactive chemical compounds in biomass pyrolysis oils has been reviewed. The hydrodeoxygenation (HDO) catalysts have been discussed including traditional HDO catalysts such as CoMo/Al2O3 and NiMo/Al2O3 catalysts and transition metal catalysts (noble metals). The mechanism of HDO of lignin-derived phenols was analyzed on the basis of different model compounds. The kinetics of HDO of different lignin-derived model compounds has been investigated. The diversity of bio-oils leads to the complexities of HDO kinetics. The techno-economic analysis indicates that a series of major technical and economical efforts still have to be investigated in details before scaling up the HDO of lignin-derived phenols in existed refinery infrastructure. Examples of future investigation of HDO include significant challenges of improving catalysts and optimum operation conditions, further understanding of kinetics of complex bio-oils, and the availability of sustainable and cost-effective hydrogen source. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：470 / 477

页数：8

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