Decomposition of ethoxyethynyl(trimethyl)tin -: Studied by 119Sn and 13C NMR spectroscopy

被引：3

作者：

Wrackmeyer, B

Ponomarev, SV

机构：

[1] Univ Bayreuth, Anorgan Chem Lab, D-95440 Bayreuth, Germany

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1999年 / 54卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

alkynes; ketenes; tin; NMR data;

D O I：

10.1515/znb-1999-0601

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermally induced decomposition of ethoxyethynyl (trimethyl)tin (1) was studied by Sn-119 NMR which revealed the formation of bis(trimethylstannyl) ketene (2) as the major product, bis(trimethylstannyl) acetic acid ethyl ester (3) as a minor product, and a small amount of tetramethyltin (4). Full NMR data sets, including coupling constants and isotope induced chemical shifts (1)Delta(12/13)C(Sn-119) are provided for 1- 3. The first example of ultra-high resolution Sn-119 NMR is shown.

引用

页码：705 / 708

页数：4