Anion-assisted amidinium exchange and metathesis

被引：1
|
作者：
Borodin, Oleg [1 ]
Shchukin, Yevhenii [1 ]
Schmid, Jonas [1 ]
von Delius, Max [1 ]
机构：
[1] Ulm Univ, Inst Organ Chem, Albert Einstein Allee 11, D-89081 Ulm, Germany
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 73期
基金：
欧洲研究理事会;
关键词：
DYNAMIC COVALENT; CHEMISTRY; CATALYSIS; CLICK; TOOL;
D O I：
10.1039/d2cc03425e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dynamic covalent chemistry has become an invaluable tool for the design and preparation of adaptable yet robust molecular systems. Herein we explore the scope of a largely overlooked dynamic covalent reaction - amidinium exchange - and report on conditions that allow formal amidinium metathesis reactions.
引用
收藏
页码：10178 / 10181
页数：4
相关论文
共 50 条
  • [21] NOVEL BORATE ANION-ASSISTED CYCLIZATION - FACILE REARRANGEMENT OF 1-CYCLOPROPYLIDENEALKYLBORANES TO HOMOPROPARGYLBORANES
    MERRILL, RE
    ALLEN, JL
    ABRAMOVITCH, A
    NEGISHI, E
    TETRAHEDRON LETTERS, 1977, (12) : 1019 - 1022
  • [22] Anion-Assisted Supramolecular Polymerization: From Achiral AB-Type Monomers to Chiral Assemblies
    Capici, Calogero
    Cohen, Yoram
    D'Urso, Alessandro
    Gattuso, Giuseppe
    Notti, Anna
    Pappalardo, Andrea
    Pappalardo, Sebastiano
    Parisi, Melchiorre F.
    Purrello, Roberto
    Slovak, Sarit
    Villari, Valentina
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (50) : 11956 - 11961
  • [23] Structure, function and interfacial allosterism in phospholipase A2: insight from the anion-assisted dimer
    Bahnson, BJ
    ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 2005, 433 (01) : 96 - 106
  • [24] The basis for k*cat impairment in prophospholipase A2 from the anion-assisted dimer structure
    Epstein, TM
    Yu, BZ
    Pan, YH
    Tutton, SP
    Maliwal, BP
    Jain, MK
    Bahnson, BJ
    BIOCHEMISTRY, 2001, 40 (38) : 11411 - 11422
  • [25] A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly
    Zhang, Ya-Jun
    Chen, Cheng
    Cai, Li-Xuan
    Yang, Xiao-Dong
    Zhang, Jie
    INORGANIC CHEMISTRY, 2017, 56 (17) : 10529 - 10534
  • [26] Electrolyte anion-assisted charge transportation in poly(oxoammonium cation/nitroxyl radical) redox gels
    Nakahara, Kentaro
    Oyaizu, Kenichi
    Nishide, Hiroyuki
    JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (27) : 13669 - 13673
  • [27] Anion-Assisted Formation of Discrete Homodimeric and Heterotetrameric Assemblies by Benzene Based Protonated Heteroaryl Receptors
    Arunachalam, M.
    Chakraborty, Souray
    Marivel, S.
    Ghosh, Pradyut
    CRYSTAL GROWTH & DESIGN, 2012, 12 (04) : 2097 - 2108
  • [28] Inorganic anion-assisted supramolecular assemblies of bent dipyridines: effects of anionic geometries on hydrogen-bonding networks
    Ding, Xue-Hua
    Wang, Shi
    Li, Yong-Hua
    Huang, Wei
    INORGANIC CHEMISTRY FRONTIERS, 2015, 2 (03): : 263 - 272
  • [29] Stability and kinetics of acid- and anion-assisted dissociation reactions of hexaamine macrobicyclic mercury(II) complexes
    Grondahl, L
    Hammershoi, A
    Sargeson, AM
    Thom, VJ
    INORGANIC CHEMISTRY, 1997, 36 (23) : 5396 - 5403
  • [30] Anion-assisted Fe(III)-coordination supramolecular systems based on 2,6-diacetylpyridine dihydrazone
    Danilescu, Olga
    Bulhac, Ion
    Bourosh, Paulina N.
    Croitor, Lilia
    POLYHEDRON, 2022, 215
12345