EPR testing of the concentration of paramagnetic centers using standards

被引:1
作者
Sobolev, A. S. [1 ]
机构
[1] Russian Acad Sci, Ural Div, Inst Met Phys, Ekaterinburg 620041, Russia
关键词
electron paramagnetic resonance; testing; paramagnetic centers; concentration; standards; test object; MAGNETIC-RESONANCE METHODS; FEASIBILITY; STATE;
D O I
10.1134/S106183091303008X
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A calculation model for the evaluation of the concentrations of paramagnetic centers in specimens using their electron paramagnetic resonance spectra in the form of single derivatives of resonance curves is developed. It is shown that using a correcting factor to account for differences of the shapes of the resonance curves of standards, which are based on a polycrystalline radical of the alpha, alpha'-diphenyl-beta-picrylhydrazyl type, and tested objects allows the error in the evaluation of the paramagnetic-center concentration to be reduced to a practically acceptable level of 30%.
引用
收藏
页码:170 / 177
页数:8
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