New Approaches to Functionalizing Metal-Coordinated N2

被引：30

作者：

Andino, Jose G. ^{[1
]}

Mazumder, Shivnath ^{[1
]}

Pal, Kuntal ^{[1
]}

Caulton, Kenneth G. ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 18期

基金：

美国国家科学基金会;

关键词：

alkynes; click chemistry; high-energy molecules; nitrogen fixation; thermodynamics; DINITROGEN COMPLEXES BEARING; HETEROCYCLIC CARBENE LIGANDS; SIDE-ON; N-2; HYDROGENATION; TERMINAL ALKYNES; BOND FORMATION; REDUCTION; CLEAVAGE; ACTIVATION; REACTIVITY;

D O I：

10.1002/anie.201209168

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N2, can do: Converting the refractory molecule N2 into synthetic chemicals is thermodynamically preferred when the derivatizing reactant is a "high-energy molecule", one with a positive enthalpy of formation. Alkynes and allenes are thus targeted for this purpose (see scheme), and a range of likely products are identified, especially those with N-N bonds, including bipyrroles. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4726 / 4732

页数：7

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