Are metal-free pristine carbon nanotubes electrocatalytically active?

被引:49
作者
Cheng, Yi
Zhang, Jin
Jiang, San Ping [1 ]
机构
[1] Curtin Univ, Fuels & Energy Technol Inst, Perth, WA 6102, Australia
基金
澳大利亚研究理事会;
关键词
OXYGEN REDUCTION; EVOLUTION REACTION; ELECTRODES; WATER; DEPENDENCE; SURFACES; HYDROGEN;
D O I
10.1039/c5cc02218e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-free (i.e., residual metallic impurities-blocked) carbon nanotubes (CNTs) do show electrocatalytic activity for H-2 evolution, O-2 evolution and O-2 reduction reactions (HER, OER & ORR) in alkaline solutions, but their activities strongly depend on the number of walls or inner tubes with a maximum for CNTs with 2-3 walls.
引用
收藏
页码:13764 / 13767
页数:4
相关论文
共 26 条
[1]   Chemisorption of molecular hydrogen on carbon nanotubes: A route to effective hydrogen storage? [J].
Bilic, Ante ;
Gale, Julian D. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (32) :12568-12575
[2]   Noncovalent interactions of molecules with single walled carbon nanotubes [J].
Britz, David A. ;
Khlobystov, Andrei N. .
CHEMICAL SOCIETY REVIEWS, 2006, 35 (07) :637-659
[3]   Nanoscale Electrocatalysis: Visualizing Oxygen Reduction at Pristine, Kinked, and Oxidized Sites on Individual Carbon Nanotubes [J].
Byers, Joshua C. ;
Gueell, Aleix G. ;
Unwin, Patrick R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (32) :11252-11255
[4]   Reactivity of the convex and concave surfaces of single-walled carbon nanotubes (SWCNTs) towards addition reactions: Dependence on the carbon-atom pyramidalization [J].
Chen, ZF ;
Thiel, W ;
Hirsch, A .
CHEMPHYSCHEM, 2003, 4 (01) :93-+
[5]   Pristine carbon nanotubes as non-metal electrocatalysts for oxygen evolution reaction of water splitting [J].
Cheng, Yi ;
Xu, Changvvei ;
Jia, Lichao ;
Gale, Julian D. ;
Zhang, Lili ;
Liu, Chang ;
Shen, Pei Kang ;
Jiang, San Ping .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 163 :96-104
[6]   ELECTRON-TRANSFER THROUGH THIN ANODIC OXIDE-FILMS DURING THE OXYGEN EVOLUTION REACTIONS AT PT ELECTRODES .1. ACID-SOLUTIONS [J].
DAMJANOVIC, A ;
BIRSS, VI ;
BOUDREAUX, DS .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (09) :2549-2555
[7]   Chirality-Dependent Transport in Double-Walled Carbon Nanotube Assemblies: The Role of Inner Tubes [J].
Fujisawa, Kazunori ;
Komiyama, Keita ;
Muramatsu, Hiroyuki ;
Shimamoto, Daisuke ;
Tojo, Tomohiro ;
Kim, Yoong Ahm ;
Hayashi, Takuya ;
Endo, Morinobu ;
Oshida, Kyoichi ;
Terrones, Mauricio ;
Dresselhaus, Mildred S. .
ACS NANO, 2011, 5 (09) :7547-7554
[8]   THE EFFECTS OF CYANIDE ON THE ELECTROCHEMICAL PROPERTIES OF TRANSITION-METAL MACROCYCLES FOR OXYGEN REDUCTION IN ALKALINE-SOLUTIONS [J].
GUPTA, S ;
FIERRO, C ;
YEAGER, E .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 306 (1-2) :239-250
[9]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[10]   REACTIVE DEPOSITION OF COBALT ELECTRODES .4. ALKALINE WATER ELECTROLYSIS [J].
JIANG, SP ;
TSEUNG, ACC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (05) :1216-1222