CO2-Responsive polymer materials

被引:186
作者
Liu, Hanbin [2 ]
Lin, Shaojian [3 ]
Feng, Yujun [1 ,2 ]
Theato, Patrick [3 ]
机构
[1] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[3] Univ Hamburg, Inst Tech & Macromol Chem, D-20146 Hamburg, Germany
基金
中国国家自然科学基金;
关键词
REVERSIBLE FIXATION-RELEASE; WORM-LIKE MICELLES; CARBON-DIOXIDE; CO2; CAPTURE; EMULSION POLYMERIZATION; CO2-SWITCHABLE POLYMERS; TRIBLOCK COPOLYMERS; GOLD NANOPARTICLES; SURFACTANT; PH;
D O I
10.1039/c6py01101b
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
CO2-Responsive polymer materials have received enormous attention in recent years, since CO2 as a new trigger has many advantages such as abundant availability, low cost, energy-saving, environment-friendly, non-toxic, good reversibility as well as great biocompatibility. In this review, we first discuss the virtues of CO2-responsiveness by comparing with traditional stimuli-sensitive materials that respond to pH, light, or redox stimuli. Then, the chemical fundamentals of CO2-responsive polymer materials are revealed including recently discovered "unexpected" CO2-sensitive features. Recent progress of CO2-responsive polymer materials is highlighted followed by various CO2-responsive "smart" polymer systems. Finally, challenges and outlooks in this area are discussed.
引用
收藏
页码:12 / 23
页数:12
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