Nanoscratch and friction: An innovative approach to understand the tribological behaviour of poly(amide) fibres

The analysis of the wear resistance of polymeric fibres requires a better understanding of both their abrasive scratch behaviour and their frictional response. These aspects have been investigated at the nanometre scale using the resources of a modified surface force apparatus. In an attempt to simulate the abrasive wear losses, nanomachining experiments have been carried out which consists in the repeated scratching of a portion of the fibre surface by the rigid indenter. However, an analysis of the resulting surface topography indicated a significant plastic grooving of the fibre surface with no evidence of wear losses as it was observed at the macroscopic scale. Single pass nanoscratch experiments realised at various sliding speeds also allow discussing the relative contributions of both the material viscoplasticity and the tip/material local interactions on the frictional response. When the sliding speed was incrementally changed during a scratch experiment, it was observed that the associated friction variation was accommodated on a 50 nm distance, independently of the sliding speed. (c) 2005 Elsevier Ltd. All rights reserved.