Silver-Palladium Nanoalloys Modified Carbon Ionic Liquid Electrode with Enhanced Electrocatalytic Activity Towards Formaldehyde Oxidation

被引：30

作者：

Safavi, Afsaneh ^{[1
,2
]}

Momeni, Safieh ^{[1
]}

Tohidi, Maryam ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz, Iran

[2] Shiraz Univ, Nanotechnol Res Inst, Shiraz, Iran

来源：

ELECTROANALYSIS | 2012年 / 24卷 / 10期

关键词：

AgPd nanoalloys; Carbon ionic liquid electrode; Formaldehyde; Microwave; Ionic liquid; FORMIC-ACID; AMPEROMETRIC DETECTION; NANOPARTICLES; PLATINUM; COMPOSITE; BEHAVIOR; METHANOL; ALLOYS; SENSOR;

D O I：

10.1002/elan.201200257

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Electrocatalysis of the oxidation of formaldehyde on silver-palladium-modified carbon ionic liquid electrode (AgPd/CILE) was investigated in 0.1 M NaOH. The electrochemical performance of the AgPd/CILE was compared with those of Pd/CILE and Ag/CILE. Ag plays an important role in the catalytic performance of AgPd nanocatalyst and yields an excellent antifouling effect. Amperometric measurements showed that AgPd/CILE is a promising sensor for the detection of formaldehyde in the range of 10.0 mu M70.0 mM with a sensitivity of 240.6 mu A?mM-1?cm-2 and a detection limit of 2 mu M. The method is free from interference of methanol, ethanol and formic acid.

引用

页码：1981 / 1988

页数：8

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