TANDEM AND SELECTIVE CONVERSION OF TETRAHYDROPYRANYL AND SILYL ETHERS TO OXIMES CATALYZED WITH TRICHLOROISOCYANURIC ACID

被引：3

作者：

Aghapour, Ghasem ^{[1
]}

Abbaszadeh, Zeinab ^{[1
]}

机构：

[1] Damghan Univ, Sch Chem, Damghan 36715364, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2015年 / 190卷 / 09期

关键词：

Tetrahydropyranyl ether; silyl ether; oxime; trichloroisocyanuric acid; tandem synthesis; FACILE CONVERSION; PRIMARY AMIDES; EFFICIENT; ALCOHOLS; ALDEHYDES; ALDOXIMES; NITRILES; MILD; 6-DICYANOBENZOQUINONE; 3-DICHLORO-5;

D O I：

10.1080/10426507.2014.990015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Direct and oxidative conversion of tetrahydropyranyl and silyl ethers to oximes is described using trichloroisocyanuric acid (TCCA) as a relatively stable and inexpensive oxidant surprisingly in a catalytic amount and hydroxylamine hydrochloride under solvent-free conditions. Oximes can be synthesized from these protected alcohols in the presence of some other functional groups with excellent chemoselectivity using the present tandem catalytic method.

引用

页码：1464 / 1470

页数：7